Submit Manuscript | http://medcraveonline.com
Introduction
The development of materials has provided researchers with
more powerful instruments, methods and building blocks to create
outstanding materials technology and devices.
1
The discovery of
new materials have provided scientists, maybe for the frst time,
with the possibility of exploring, modifying and constructing an
artifcial world as complex as nature from a fundamental level. The
intermetallic materials, having very high specifc strength but poor
ductility, require special processing techniques to develop appropriate
microstructure for adequate ductility or toughness for successful use
in structural applications.
2
Non–equilibrium processing of materials
is often advantageous due to the possibility of producing metastable
microstructure with improved properties.
3–5
Among the no equilibrium
techniques developed during the past few decades to synthesize novel
materials include rapid solidifcation from the liquid state, mechanical
alloying/ milling, plasma processing, vapour deposition, ion or
electron or neutron irradiation.
6,7
As an important and emerging class
of no equilibrium materials, such as quasicrystalline alloys have drawn
wide attention in the recent years.
8–10
Quasicrystalline materials are of
interest because of their fundamentally new microstructure and phase
dependent novel properties not manifested by identical materials
with coarse microstructure.
11
Improvement in terms of mechanical
properties includes both increase in strength as well as ductility
and fracture toughness due to a periodic structures. Aside from the
peculiar structures, quasicrystals also exhibit much unexpected
properties such as high hardness, low surface energy, high oxidation
resistance, and low thermal conductivity, which make them attractive
for technological applications.
12,13
These materials can also be used as
dispersions, coatings, functional devices, consolidated materials, etc.
Rapid solidifcation of liquid metals and alloys can lead to refnement
of grain size, formation of new metastable quasicrystalline phases by
suppression of equilibrium solidifcation process. The quasicrystalline
materials can be synthesized by mechanical alloying, which is a solid
state powder processing technique involving repeated cold welding,
mechanically activated interdiffusion, fragmentation and dynamic
recrystallization of powder particles in a high energy ball mill, is an
ideal processing route to develop nanoquasicrystalline materials at
ambient temperature.
14,15
Quasicrystal
Quasicrystal phases are a novel class of intermetallics compou-
nds that exhibit conventionally forbidden rotational symmetries in
their diffraction patterns, which are incompatible with translational
periodicity.
16
The breakthrough on rapidly solidifed Al–14% Mn
alloys have created new concepts of ordered but no periodic atomic
arrangements which exhibit sharp diffraction peaks with icoshahe-
dral symmetry (m 35). For which he was awarded the Nobel Prize
in Chemistry in 2011. Using transmission electron microscopy and
associated high–energy electron diffraction, Shechtman made the key
observation that rapidly–quenched Al
86
Mn
14
alloy forms small par-
ticles in which the nature and relative orientations of the rotational
axes could only be explained with icosahedral symmetry as shown
in (Figure 1). Furthermore, Shechtman found that these particles did
not exhibit twinning, an effect that can sometimes lead to spurious
indications of icosahedral symmetry in crystalline materials, notably
gold. The icosahedral point group is incompatible with translational
periodicity. The sharpness of the diffraction peaks was explained until
this time on the basis of the periodicity of the crystalline materials.
The diffraction patterns simulated from these structures are startlin-
gly close to those observed for the icosahederal phase and this phase
was termed as a quasicrystal. The mathematics of diffraction does not
necessarily require periodicity; this was discussed by Mackay befo-
re the discovery of quasicrystals.
17
The Mackay extended the idea of
Penrose, who had developed a scheme of flling space a periodically
by a fnite number of tiles.
18
Mackay constructed the three dimen-
sional analogue tiles and stressed their importance in the context of
crystallography. A Penrose tiling is a non–periodic tiling generated by
and a periodic lay down. The aperiodicity of prototypes implies that a
shifted copy of a tiling will never match the original as shown (Figure
1). The tiling uses a pair of rhombuses with equal sides but different
angles. Ordinary rhombus–shaped tiles can be used to tile the plane
Material Sci & Eng. 2017;1(1):1‒3 1
© 2017 Yadav. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits
unrestricted use, distribution, and build upon your work non-commercially.
Quasicrystal: a beautiful morphology and diffraction
pattern
Volume 1 Issue 1 - 2017
Yadav TP
Department of Physics, Banaras Hindu University, India
Correspondence: Yadav TP, Department of Physics, Institute
of Science, Hydrogen Energy Centre, Centre of Advanced Study,
Banaras Hindu University,Varanasi–221005, India, Tel 91–542–
2307307, Fax 91–542–2368468, Email yadavtp@gmail.com
Received: February 13, 2017 | Published: April 19, 2017
Abstract
The synthesis of quasicrystalline phases in complex metallic alloys appears to be
advantageous for fundamental research as well as practical application. Studies
on quasicrystals and their applications have been research frontiers in chemistry,
physics, mathematics, materials science and metallurgy in the past few decades. The
remarkable progress has been made in the formation, growth and phase stability,
structure and modeling, mathematics of quasiperiodic and a periodic structures,
physical properties (transport, magnetic, dynamical, mechanical etc.), surfaces and
over layers, applications etc. However, the structural solution of the quasicrystal is
still under debate and it will provide a broad aspect for future development and guide
the investigations of different aspects of quasicrystals. Therefore, a review on the
quasicrystal may be attractive for material science & engineering community.
Keywords: intermetallic, nanostructured, quasicrystal, mechanical, alloying/
milling, rapid solidification
Material Science & Engineering International Journal
Mini Review
Open Access