IDENTIFIKASI POLISIKLIK AROMATIK HIDROKARBON (PAH) PADA EMISI KENDARAAN BERMOTOR DENGAN WHATMAN FILTER PAPER PM 10 Jakfar Shadiq, Mohammad F. Rahman*, Arinto Y.P. Wardoyo Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Brawijaya Jl. Veteran Malang 65145 *Alamat korespondensi, Tel : +62-341-575838, Fax : +62-341-575835 Email: m_farid@ub.ac.id ABSTRAK Penelitian ini bertujuan untuk identifikasi komponen PAH dan partikulat dari emisi kendaraan bermotor. Penangkapan komponen PAH dan partikulat dari emisi kendaraan bermotor menggunakan Whatman Filter Paper PM 10 selama 60 menit . Selanjutnya Whatman Filter Paper PM 10 diisolasi menggunakan soxhlet selama 10 jam dengan menggunakan pelarut diklorometana. Ekstrak yang diperoleh dipekatkan dengan gas nitrogen, Kemudian dipisahkan dengan kromatografi kolom dan dikarakterisasi menggunakan kromatografi lapis tipis. Sampel dianalisis menggunakan Kromatografi Gas Spektroskopi Massa (KG-SM). Hasil dari emisi kendaraan bermotor menunjukkan adanya beberapa komponen PAH yang sebagian besar terdiri dari C-(3-Vinyl-benzo[ghi]fluoranthen-4-yl)- methylamine, 3-Methyl-1,2,3,4-tetrahydro-anthracen-2-ylamine, and C-(3-Vinyl- naphthalen-2-yl)- methylamine. Kata kunci: PAH, Partikulat, Soxhlet , KG-SM. ABSTRACT This study was aimed to identify PAHs componds in PM 10 emitted by motor cycles. The PM 10 particulates were trapped by a whatman filter paper PM 10 for 60 minutes. The filter was isolated using soxhlet extraction for 10 hours with dichloromethane solvent, the solution was extracted by a nitrogen gases. Then the solution was separated using a column chromatography and characterized using thin layer chromatography. Finally the samples was analyzed using a GC-MS. The results showed that the PM 10 emission from motor cycles contained of a several PAHs with the relativity large amount of C-(3-Vinyl- benzo[ghi]fluoranthen-4-yl)-methylamine, 3-Methyl-1,2,3,4-tetrahydro-anthracen-2-ylamine, and C-(3- Vinyl-naphthalen-2-yl)-methylamine. Keywords: PAH, Particulate Matter, Soxhlet, GC-MS 513 KIMIA.STUDENTJOURNAL, Vol. 2, No. 2, pp. 513 - 519, UNIVERSITAS BRAWIJAYA MALANG Received 29 October 2014, Accepted 29 October 2014, Published online 30 October 2014 brought to you by CORE View metadata, citation and similar papers at core.ac.uk provided by Jurnal Ilmu Kimia Universitas Brawijaya