J. of Supercritical Fluids 76 (2013) 54–60
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The Journal of Supercritical Fluids
jou rn al h om epa ge: www.elsevier.com/locate/supflu
Supercritical carbon dioxide Brayton cycle for concentrated solar power
Pardeep Garg, Pramod Kumar
∗
, Kandadai Srinivasan
Department of Mechanical Engineering, Indian Institute of Science, Bangalore 560 012, India
a r t i c l e i n f o
Article history:
Received 12 December 2012
Received in revised form 4 January 2013
Accepted 13 January 2013
Keywords:
Supercritical CO2
Brayton cycle
Solar energy
Irreversibility
a b s t r a c t
Supercritical carbon dioxide based Brayton cycle for possible concentrated solar power applications is
investigated and compared with trans- and sub-critical operations of the same fluid. Thermal efficiency,
specific work output and magnitude of irreversibility generation are used as some of the performance
indicators. While the thermal efficiency increases almost linearly with low side pressure in the sub- and
trans-critical cycles, it attains a maximum in the supercritical regime at ∼85 bar after which there are
diminishing returns on increasing the low side pressure. It is also found that supercritical cycle is capable
of producing power with a thermal efficiency of >30% even at a lower source temperature (820 K) and
accounting for foreseeable non-idealities albeit with a higher turbine inlet pressure (∼300 bar) which
is not matched by a conventional sub-critical cycle even with a high source temperature of 978 K. The
reasons for lower efficiency than in an ideal cycle are extracted from an irreversibility analysis of compo-
nents, namely, compressor, regenerator, turbine and gas cooler. Low sensitivity to the source temperature
and extremely small volumetric flow rates in the supercritical cycle could offset the drawback of high
pressures through a compact system.
© 2013 Elsevier B.V. All rights reserved.
1. Introduction
Globally increasing electrical energy demands and environ-
mental concerns preventing its matching with supply has posed
challenges to the engineering community to look for alternative
means of bridging the gap. A large fraction of that demand is
met from water based power plants either from hydroelectric
or thermal energy derived from fossil fuels or nuclear reactors.
Environmental emotions are preventing addition of capacities
to either of those categories of power plants. Distributed power
generation, using renewable energy and non-water based working
fluids together offer opportunities to meet the exigencies. In the
past three decades there has been a spurt in research reporting
interesting results on choice of working fluids for organic Rankine
cycle (ORC) based power generation. Available options can be
categorized as halocarbons [1], which have either or both of ozone
depletion potential (ODP) and global warming potential (GWP) or
hydrocarbons which are flammable [2] or mixtures [3]. Our earlier
research addressed the issues of avoiding ODP, reducing GWP and
suppressing flammability by adopting mixtures of hydrocarbons
with either R-245fa [4] or carbon dioxide [5]. An approach adopted
by the refrigeration community, which is strongly advocating use
∗
Corresponding author. Tel.: +91 80 2293 3361;
fax: +91 80 2360 4536/3260 4356.
E-mail addresses: pramod@mecheng.iisc.ernet.in, pramod k24@yahoo.com
(P. Kumar).
of carbon dioxide as a working fluid [6], prompted us to investigate
this fluid also as a Brayton cycle working fluid for power genera-
tion. Credence to this philosophy is lent by literature on this topic
dating back to 1950 [7] and reasonably analyzed in 1960s [8–10].
The possibility of supercritical carbon dioxide (S-CO
2
) cycle for
nuclear applications [11,12], where heat source temperatures are
in the range 600–700
◦
C, steers to infer that for concentrated solar
power generation also, perhaps, this cycle could be adoptable. This
is corroborated by work of Chen et al. [13] who found transcritical
CO
2
(T-CO
2
) Rankine cycle to be more compact, eco-friendly and
devoid of pinch point in the heat exchanger. T-CO
2
operating with
a sink temperature of -50
◦
C, attainable with LNG evaporation,
has been studied [14,15]. Yamaguchi et al. [16] have tried trans-
critical condensing cycle with reasonably good efficiencies even
at a low source temperature of ∼440 K. Three options available
with entirely gaseous phase operation of carbon dioxide based
Brayton cycle are (a) conventional cycle operating entirely below
critical pressure (SN-CO
2
), (b) transcritical non-condensing cycle
with the upper cycle pressure being in the supercritical region
(TN-CO
2
), and (c) supercritical cycle with low side pressure also
being supercritical (S-CO
2
, this notation retained to be the same
as that used in literature [11,12]). Objective of this paper is to
explore all the three CO
2
Brayton cycles with specific application
to concentrated solar power adoptable for distributed power
generation for rural and remote settlements. Figs. 1 and 2 show
the three possibilities on the pressure-enthalpy and temperature-
entropy planes at 873 K source temperature. An assessment is
made of the potential of these options through a set of performance
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http://dx.doi.org/10.1016/j.supflu.2013.01.010