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ScienceDirect
Materials Today: Proceedings 4 (2017) 6948–6953
www.elsevier.com/locate/procedia
2214-7853 © 2017 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the Conference Committee Members of NANOTEXNOLOGY2016 (13th International
Conference on Nanosciences & Nanotechnologies & 9th International Symposium on Flexible Organic Electronics).
13th International Conference on Nanosciences & Nanotechnologies & 9th International
Symposium on Flexible Organic Electronics
Synthesis, processing and characterization of FeMnGa nanoparticles
for permanent magnet applications
G. Sempros
a,*
, K. Kanari
a
, C. Sarafidis
a
, M. Gjoka
b
, N. Lupu
c
, G. Ababei
c
, D. Niarchos
b
,
O. Kalogirou
a
a
Dept. of Physics, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
b
Institute of Nanoscience and Nanotechnology, NCSR “Demokritos”, Athens, Greece
c
National Institute of R&D for Technical Physics, 47 Mangeron Blvd., 700050 Iasi, Romania
Abstract
In recent years, there is a great demand in materials suitable for permanent magnets which led to shortages in the
supply of rare earth elements, a basic ingredient of high performance magnets. Research for rare earth free magnetic
materials is considered as a viable alternative. Various Heusler alloys are investigated as possible candidates.
Among them, the binary compound Mn
X
Ga has gained interest. A method of improving the magnetic properties of
intermetallic compounds is the introduction of a magnetic atom like Fe in replacement of a 3d metal, in our case, by
replacing a quantity of Mn with Fe. In this study Mn
0.4
Fe
0.3
Ga
0.3
alloys were prepared in a high purity Ar atmosphere
with the arc-melting technique followed by melt-spinning in order to get nanostructured ribbons. The samples were
further treated (annealing, ball milling) in order to tune the microstructure and obtain single phase samples with
optimum magnetic properties. Magnetization measurements were performed by using a Vibrating Sample
Magnetometer (VSM), versus temperature and field. The structure of the samples was observed with the X-Ray
Diffraction Patterns (XRD). The L1
2
structure was observed for the first time, among the other ones D0
19
and L2
1
which are already observed in Mn
3
Ga studies. A deeper observation was performed with a Scanning Electron
Microscope (SEM). Saturation magnetization of the basic material was measured at 81.4 Am
2
/kg while remanence
and coercive field were low. The effect of the grain size on the magnetic properties, due to ball milling, is presented.
© 2017 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the Conference Committee Members of NANOTEXNOLOGY2016 (13th
International Conference on Nanosciences & Nanotechnologies & 9th International Symposium on Flexible Organic
Electronics).
Keywords: Ball milling; magnetic properties; intermetallic compound
*corresponding author: gsempros@physics.auth.gr