2003 © American Water Works Association
YAVICH ET AL | PEER-REVIEWED | 95:4 • JOURNAL AWWA | APRIL 2003 159
Use of Ozonation
and FBT
to control THM precursors
This study evaluated ozonation in combination with biological fluidized-bed treatment (FBT)
for control of trihalomethane (THM) precursors in drinking water. THM precursors were
represented by several surrogate parameters, including total organic carbon, ultraviolet
absorbance measured at 254 nm, humic substances, and THM formation potential. The study
was conducted using a continuously operated ozonation–FBT system. No pretreatment was
provided. In addition, biofiltration and bench-scale ozonation systems were used to compare
the biodegradation efficiency of FBT with that of biofiltration and to investigate the effect of
ozonation on biodegradation efficiency. The study showed that the combined ozonation–FBT
process was effective in removing THM precursors and reducing turbidity in drinking water.
Preliminary cost estimates indicate that the ozonation–FBT process may be a viable alternative
to conventional coagulation processes that require additional steps, such as ozonation and
biological activated carbon filtration for the control of disinfection by-products in drinking water.
BY ALEX A. YAVICH
AND SUSAN J. MASTEN
he formation of disinfection by-products (DBPs) is a major concern of
drinking water utilities. Trihalomethanes (THMs), the dominant DBP
species formed during chlorination, have been identified as potential
carcinogens in both toxicological and epidemiological studies (Black et
al, 1996). Under Stage 1 of the Disinfectants/DBP Rule, the US Envi-
ronmental Protection Agency (USEPA) reduced the THM maximum contaminant
level in finished water from 100 to 80 μg/L (USEPA, 1998). The agency has pro-
posed regulations to further limit levels of THMs and other DBPs (Arora et al,
1997; Pontius, 1995; USEPA, 1994). Nearly 70% of surface water utilities will
be affected by these regulations (Black et al, 1996), and the consequences for small
utilities are of particular concern. In compliance with the Safe Drinking Water Act
amendments, USEPA is required to identify technologies that are technically and
economically feasible for small systems serving up to 10,000 people (NRC,
1997).
The addition of ozone prior to chlorination has been identified as an impor-
tant step in the minimization of THM formation to meet current and future
USEPA standards (Ozone News, 1997). These more-stringent water quality reg-
ulations have resulted in an increase in the acceptance of ozone by US water
providers (Urfer et al, 1997). Since the early 1980s, the number of US drinking
water treatment plants employing ozone has risen rapidly from about 10 to
approximately 300 (Ozone News, 1997).
T