Research Article
The Production of Zeolite Y Catalyst From Palm Kernel Shell for
Fluid Catalytic Cracking Unit
Angela Mamudu ,
1
Moses Emetere ,
2
Felix Ishola ,
3
and Dorcas Lawal
1
1
Department of Chemical Engineering, Covenant University, Ota, Nigeria
2
Department of Physics, Covenant University, Ota, Nigeria
3
Department of Mechanical Engineering, Covenant University, Ota, Nigeria
Correspondence should be addressed to Angela Mamudu; angela.mamudu@covenantuniversity.edu.ng
Received 15 June 2020; Revised 15 September 2020; Accepted 17 March 2021; Published 31 March 2021
Academic Editor: Ho SoonMin
Copyright © 2021 Angela Mamudu et al. is is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is
properly cited.
Exorbitant costs of fluid catalytic cracking unit (FCCU) catalysts coupled with their ever-increasing demand have led researchers
to develop alternative materials from indigenous sources. In this study, the zeolite Y component of the FCCU catalyst was
synthesized from palm kernel shells. Leaching was carried out with the aid of citric acid to remove impurities. e synthesis
process was done using alkaline hydrothermal treatment while varying reagent concentration and reaction time. e resultant
products were characterized using XRF, XRD, FTIR, BET, and SEM analysis. e XRD and XRF showed a high silicate content
level, while an 85% reduction in iron oxide impurities was observed after leaching. e process carried out at a duration of 9 hours,
a temperature of 80
°
C with a NaOH molarity strength of 2 mol/L, had the highest SiO2 and Si/Al ratio value. A spongy, porous
zeolite crystal was formed with the presence of hydroxyls in its sodalite cage. All samples had a combination of types II & I
adsorption isotherms, Si/Al ratio of 2–5, and specific surface area within 80–260 m
2
/g, which indicates the presence of inter-
mediate mesostructured Zeolite Y catalyst. Synthesized zeolite Y showed a more significant gap in its structural formation as the
addition of NaOH decreased the grain size by 14.3%. FTIR highlighted the significant functional groups present in the novel
compound, which, when compared to previous works, proves its suitability.
1. Introduction
Petroleum refining is a process through which crude oil is
converted into useful products [1]. Although it has many
distinct units, the conversion and separation units always
play significant roles [2]. e fluid catalytic cracking unit
(FFCU), which falls under the conversion group, remains
an indispensable unit operating in refineries. It converts
about 40% of the heavy residues gotten from both vacuum
and atmospheric distillation into lighter and more useful
products with higher octane values [3, 4]. According to
Vogt and Weckhuysen [5]; the heavy hydrocarbon mole-
cules (majorly gas oil) preheated at about 149
°
C are charged
as a feedstock into a catalyst riser containing particles of
powdered catalyst that are fluidized by the hydrocarbon
vapors. Cracking occurs within 2–4 seconds in the riser,
where the heavy molecules are broken down into lighter
and shorter chain molecules at 1 atm with a temperature
range of 520
°
C–550
°
C. Separation occurs in the distillation
column while the catalyst particles are re-generated.
One of the significant achievements that have contrib-
uted to the ever-growing popularity of the FCCU has been
the introduction of Zeolite catalysts. Zeolites are hydrated
alumina silicate materials made from inter-linked tetrahe-
dral of alumina (AlO
4
) and silica (SiO
4
). 130 out of 840
catalysts used in industrial applications are based on zeolites,
and the FCCU in petroleum refineries utilizes over 61% of
these zeolite-based catalysts. e zeolite component makes
up 10–50 wt.% of the catalyst and provides activity, stability,
and selectivity. Zeolites are produced both synthetically and
naturally, but most of the zeolites used in the FCCU are
synthetically produced. Synthetic zeolite has fewer
Hindawi
International Journal of Chemical Engineering
Volume 2021, Article ID 8871228, 8 pages
https://doi.org/10.1155/2021/8871228