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Materials Today: Proceedings 4 (2017) 11848–11856 www.materialstoday.com/proceedings
2214-7853 © 2017 Elsevier Ltd. All rights reserved.
Selection and Peer-review under responsibility of INTERNATIONAL CONFERENCE ON NANOTECHNOLOGY (ICNANO-2016).
ICNANO 2016
Photoluminescence Studies of Rare-Earth-Doped (Ce
3+
) LaAlO
3
nanopowders prepared by facile combustion route
T. Manohar
a
, S.C. Prashantha
a*
, H. Nagabhushana
b
*, K. Channakeshavalu
a
,
H.P. Nagaswarupa
a
a
Research Center, Department of Science, East West Institute of Technology, VTU, Bengaluru-560091, India.
b
Prof. C.N.R. Rao center for Advanced Materials, Tumkur University, Tumkur-572103, India.
Abstract
A green emissive with a CIE coordinate (0.179, 0.415), Ce
3+
doped Lanthunum alluminate (LaAlO
3
) rhombohedral phosphor was
prepared by solution combustion synthesis with crystallite size in the range 20-50 nm and characterized by PXRD, TEM, Uv-
Visible and photoluminescence. Optical band gap of Ce
3+
doped LaAlO
3
was estimated to be in the range 2.94-4.99 eV.
LaAlO
3
:Ce
3+
was effectively excited by NUV and characteristic PL emission confirms that, the phosphor can be a candidate for
display applications.
© 2017 Elsevier Ltd. All rights reserved.
Selection and Peer-review under responsibility of INTERNATIONAL CONFERENCE ON NANOTECHNOLOGY
(ICNANO-2016).
Key words — LaAlO
3
:Ce
3+
, Photoluminescence (PL), CIE n CCT, WLEDs.
1. Introduction
WLEDs play a crucial role in the field of solid-state lighting. They are regarded as the next- generation
illumination source due to their efficient luminescence, lifetimes, and environmental friendly nature [1]. At present,
rare-earth ions are the most frequently used activators to meet the requirements of WLEDs due to their abundant
emission colors based on the energy level transition [2,3]. Among rare-earth ions, Ce
3+
ion has a wide excitation
band which can well excited by NUV-LED chips and results in strong emission band due to the transitions from 5d
excited state to the 4f ground states(2F7/2 and 2F5/2) [4,5]. The 5d excited state of Ce
3+
is sensitive to the lattice
environment and the spectrum site of Ce
3+
might be adjusted from blue to green, yellow, and orange [6-9]. For
*
Corresponding author. Tel.: +91-98860 21344; fax: +080-232-8824
E-mail address:scphysics@gmail.com. bhushanvlc@gmail.com