Contents lists available at ScienceDirect
Colloids and Surfaces A
journal homepage: www.elsevier.com/locate/colsurfa
Facile preparation of gold-coated polydimethylsiloxane particles by in situ
reduction without pre-synthesized seed
Min-Cheol Lim
a
, Kisang Park
a,b
, Sae-Hyung Kim
b
, Gyeongsik Ok
a
, Sung-Wook Choi
a
,
Min-Ah Woo
a,
⁎
a
Korea Food Research Institute, Seongnam, Republic of Korea
b
Department of Molecular Science and Technology, Ajou University, Suwon, Republic of Korea
GRAPHICAL ABSTRACT
ARTICLE INFO
Keywords:
Gold nanoparticle
PDMS particle
Reduction
Auric acid
Sodium citrate
ABSTRACT
Herein, we develop a facile strategy for the preparation of polydimethylsiloxane (PDMS) microparticles deco-
rated with gold nanoparticles (AuNPs) by the reduction of gold chloride on the surface of PDMS microparticles
using sodium citrate. To prepare the AuNP-seeded particles, AuNP-seeded PDMS microparticles were simply
produced in situ by the reduction of a PDMS curing agent without the use of any additional reducing agents. The
resultant AuNP-seeded PDMS microparticles were further reacted with sodium citrate and gold chloride to
synthesize AuNP clusters on the PDMS microparticle surfaces. The synthesized AuNP-coated PDMS micro-
particles were extensively characterized using scanning electron microscopy, X-ray diffraction, X-ray photo-
electron spectroscopy, and UV–vis absorption spectroscopy. Notably, the surface coverage of AuNPs on the
PDMS microparticles could be easily controlled using this proposed method.
http://dx.doi.org/10.1016/j.colsurfa.2017.07.003
Received 8 June 2017; Received in revised form 3 July 2017; Accepted 4 July 2017
⁎
Corresponding author.
E-mail address: mawoo@kfri.re.kr (M.-A. Woo).
Colloids and Surfaces A 529 (2017) 916–921
0927-7757/ © 2017 Elsevier B.V. All rights reserved.
MARK