Short Communication
Modeling and optimization of CdS/CuIn
1¡x
Ga
x
Se
2
structure for solar cells applications
H. Arbouz
a
, A. Aissat
a,b,*
, J.P. Vilcot
c
a
LATSI Laboratory Faculty of Technology, University of Blida 1, BP270, 09.000 Blida, Algeria
b
LASICOM Laboratory Faculty of Sciences, University of Blida 1, BP270, 09.000 Blida, Algeria
c
Institut d'Electronique, de Micro electronique et de Nanotechnologie, UMR CNRS 8520, Universit e des Sciences et
Technologies de Lille1, Avenue Poincar e, CS 60069, 59652 Villeneuve d'Ascq, France
article info
Article history:
Received 9 March 2016
Received in revised form
10 June 2016
Accepted 11 June 2016
Available online xxx
Keywords:
Materials
Semiconductor
Solar cell
Photovoltaic
abstract
This work deals with the modeling and optimization of the CuInGaSe/CdS based structure
for photovoltaic applications. We took into consideration the effect of the gallium con-
centration and the temperature on the strain, band gap energy, absorption and efficiency of
the structure. It has been demonstrated that increasing the gallium concentration in-
creases the ban gap energy, while increasing temperature decreases it. These two pa-
rameters vary the efficiency significantly. For x ¼ 30% and T ¼ 300 K, the band gap energy is
equal to 1.15 eV with a deformation of 0.5% and efficiency around 20%. We have also found
that at this value of the band gap energy the structure absorbs most of the incident pho-
tons. Then to achieve a reliable cell based on CuInGaSe/CdS it is adequate to find a
compromise between the gallium concentration in the alloy, the temperature and the
strain.
© 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Introduction
Currently several research works tend to optimize renewable
energy in its many forms like solar thermal, wind, photovol-
taic, hydroelectric, …etc [1e3]. The photovoltaic market is
dominated by the solar cells of the first generation using
crystalline silicon as absorber material, because of its abun-
dance in the crust of the earth [4]. Despite this fact, this
technology presents some disadvantages as the necessity to
use a very pure semiconductor whose thickness is around
200 mm. The emergence of the second generation solar cells
based on thin film technology offers the possibility to reduce
material cost and open new applications by using thinner
absorbers having higher absorption coefficients with very
good optoelectronic properties. The most important materials
used as thin layer absorbers are amorphous and microcrys-
talline silicon, CdS, CdTe, CIGS and CZTS [5]. The hetero
junction CIGS(P)eCdS(n) is formed by adding a buffer layer of
CdS type n on top of the CIGS absorber. The buffer also pro-
tects the CIGS layer during the sputtering process of deposi-
tion of the following layers of the cell [6,7]. Actually, the best
efficiency recorded for the CIGS solar cell is where the CdS
buffer layer is used. But because of its toxicity owing to the
presence of Cd, other buffers have been tried and developed
* Corresponding author. LATSI Laboratory Faculty of Technology, University of Blida 1, BP270, 09.000 Blida, Algeria.
E-mail address: aissaouikader6@gmail.com (A. Aissat).
Available online at www.sciencedirect.com
ScienceDirect
journal homepage: www.elsevier.com/locate/he
international journal of hydrogen energy xxx (2016) 1 e6
http://dx.doi.org/10.1016/j.ijhydene.2016.06.104
0360-3199/© 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Please cite this article in press as: Arbouz H, et al., Modeling and optimization of CdS/CuIn
1x
Ga
x
Se
2
structure for solar cells applica-
tions, International Journal of Hydrogen Energy (2016), http://dx.doi.org/10.1016/j.ijhydene.2016.06.104