Contents lists available at ScienceDirect
Solar Energy Materials & Solar Cells
journal homepage: www.elsevier.com/locate/solmat
Surface potential investigation on interdigitated back contact solar cells by
Scanning Electron Microscopy and Kelvin Probe Force Microscopy: Effect of
electrical bias
Paul Narchi
a,b,
⁎
, Vladimir Neplokh
c
, Valerio Piazza
c
, Twan Bearda
d
, Fabien Bayle
c
,
Martin Foldyna
b
, Chiara Toccafondi
b
, Patricia Prod’homme
a
, Maria Tchernycheva
c
,
Pere Roca i Cabarrocas
b
a
TOTAL New Energies, 24 cours Michelet, 92069 Paris La Défense Cedex, France
b
LPICM, CNRS, Ecole Polytechnique, Université Paris-Saclay, 91128 Palaiseau, France
c
Institut d’Electronique Fondamentale, UMR 8622 CNRS, University Paris Sud, University Paris Saclay, 91405 Orsay, France
d
IMEC, Kapeldreef 75, B-3001 Leuven, Belgium
ARTICLE INFO
Keywords:
Interdigitated back contact
Heterojunction
Solar cells
Silicon
Kelvin Probe Force Microscopy
Scanning Electron Microscopy
ABSTRACT
Both Kelvin Probe Force Microscopy and Scanning Electron Microscopy enable assessment of the effect of
electrical bias on the surface potential of the layers of a solar cell. We report on a comprehensive comparison of
surface potential measurements on an interdigitated back contact solar cell using these two techniques.
Measurements under different values of electrical biases are performed on and between the metallic contacts.
They show a good agreement between the surface potential obtained with Kelvin Probe Force Microscopy and
the Scanning Electron Microscopy signal. In order to provide an accurate comparison, the scanned areas are
adjacent to each other and accurate repositioning is achieved thanks to a nano-indentation between the
contacts. We show that measurements under reverse bias are of interest to locate nano-defects and
measurements under forward bias are relevant to identify local series resistance issues. We suggest that a
setup combining Scanning Electron Microscopy and Kelvin Probe Force Microscopy under different values of
the electrical bias should be valuable since the former is a high throughput technique enabling measurements on
large scan areas, while the latter is a quantitative, low noise, and unintrusive local technique.
1. Introduction
Interdigitated back contact (IBC) solar cells are a promising design
to reach high conversion efficiencies. In this architecture, both p and n
contacts are positioned on the rear side of the cell with the shape of two
interdigitated combs. This design avoids reflection losses on the front
side of the cell, contrary to the case of traditional solar cells. The latest
crystalline silicon solar cells showing the record efficiencies belong to
IBC family. For instance, Sunpower has recently presented 25%
efficient industrially feasible solar cells [1] and Kaneka has announced
a 26.33% laboratory world record [2] using this design. In order to
approach the theoretical limit of 29% efficiency for crystalline silicon
solar cells [3] remaining losses have to be reduced. Among them,
electrical losses mainly come from local series resistance due to poor
local contacts and long current paths [4]. In this perspective, the
investigation of series resistance and electrical defects at the nanoscale
becomes of interest to localize the areas of power losses in IBC solar
cells. Local series resistances cause surface potential drops that can be
monitored with several characterization techniques. In this work, we
focus on two of them: Kelvin Probe Force Microscopy (KPFM) and
Scanning Electron Microscopy (SEM).
KPFM is a scanning probe microscopy technique that measures the
surface potential of a sample by monitoring the amplitude of the AFM
cantilever operated in tapping mode. KPFM has proven to be an
effective tool to investigate the electrical behavior of solar cells at the
nanoscale. For instance, measurements on the cross-section of solar
cells have enabled monitoring the effect of illumination [5] and
electrical bias [6] on the PN junction properties of solar cells.
SEM is an electron microscopy technique that is routinely used to
study the surface topography of materials at the nanoscale. However, it
http://dx.doi.org/10.1016/j.solmat.2016.12.009
Received 21 June 2016; Received in revised form 14 October 2016; Accepted 2 December 2016
⁎
Corresponding author at: TOTAL New Energies, 24 cours Michelet, 92069 Paris La Défense Cedex, France.
E-mail address: paul.narchi@polytechnique.edu (P. Narchi).
Abbreviations: AFM, Atomic Force Microscopy; a-Si, H: hydrogenated amorphous silicon; IBC, Interdigitated Back Contact Solar Cell; ITO, Indium Tin Oxide; J(V), current density –
voltage; KPFM, Kelvin Probe Force Microscopy; SE, Secondary Electrons; SEM, Scanning Electron Microscopy
Solar Energy Materials & Solar Cells 161 (2017) 263–269
0927-0248/ © 2016 Elsevier B.V. All rights reserved.
MARK