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0007-4888/19/16630386--©-2019--Springer-Science+Business-Media,-LLC
Bulletin of Experimental Biology and Medicine, Vol. 166, No. 3, January, 2019
BIOTECHNOLOGIES
Visualization and Cytotoxicity of Fluorescence-Labeled Dimeric
Magnetite-Gold Nanoparticles Conjugated with Prostate-
Specifc Membrane Antigen in Mouse Macrophages
S. K. Pirutin
1,2
, M. V. Efremova
1,3
, A. I. Yusipovich
1
, V. B. Turovetskii
1
,
G. V. Maksimov
1
, A. B. Druzhko
2
, and A. G. Mazhuga
1,3,4
Translated from Byulleten’ Eksperimental’noi Biologii i Meditsiny, Vol. 166, No. 9, pp. 362-365, September, 2018
Original article submitted November 9, 2017
We demonstrated the possibility of penetration of magnetite-gold nanoparticles conjugated
with prostate-specifc membrane antigen into mouse macrophages. It was found that after 3-h
incubation with nanoparticles in a concentration of 15 mg/liter at 37
o
C, they were seen in only
13% macrophages. In about 90% cells, the nanoparticles were detected within the cytoplasm.
Under these conditions, membrane damage was revealed in 25% cells. These results should
be taken into account in further development and application of nanomaterials for diagnostic
and therapeutic purposes in oncology.
Key Words: magnetite-gold nanoparticles; prostate-specifc membrane antigen; macro-
phages; cell membranes
1
M. V. Lomonosov Moscow State University, Moscow;
2
Institute of
Theoretical and Experimental Biophysics, Russian Academy of Sci-
ences, Pushchino, Moscow Region;
3
National University of Science
and Technology MISIS;
4
D. I. Mendeleev University of Chemical
Technology of Russia, Moscow, Russia. Address for correspondence:
pirutin@yandex.ru. S. K. Pirutin
New types of magnetic nanoparticles developed du-
ring the last decade are now widely used in cell re-
search, engineering, and biomedicine [5]. This requires
evaluation of their functional and cytotoxic properties.
Much attention is now attracted to studies of gold-
containing nanoparticles widely used in biological
research for delivering various substances into cells,
photodynamic and radiotherapy of tumors [3,6]. These
particles also uses for in the diagnosis and treatment
of various diseases [7].
In particular, magnetic nanoparticle are consid-
ered as contrast agents during magnetic resonance
imaging (MRI) [11]. The use of MRI in combination
with dimeric magnetite-gold nanoparticles (MGN) se-
lectively binding to target organs provides additional
opportunities for diagnosing and visualization of tu-
mors that are diffcult to detect by traditional methods,
e.g. X-ray computed tomography [13]. However, the
effectiveness of nanoparticles, depends not only on
their specifc binding with the target cells, but also on
nonspecifc binding with other cells, especially with
macrophages.
Many contrast agents for MRI based on magnetite
nanoparticle cannot be used in clinical practice due
to serious side effects [14]. Preliminary studies [9]
have demonstrated that absorption of nanoparticles can
cause death of liver cells.
We studied the possibility of nonspecifc penetra-
tion of fuorescent conjugates of modifed MGN with
prostate-specifc membrane antigen (PSMA) devel-
oped for specifc binding to human prostate cancer
cells [10] (Fig. 1), into peritoneal mouse macrophages
and evaluated cytotoxicity of these nanoparticles.
DOI 10.1007/s10517-019-04356-9