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Materials Today: Proceedings 21 (2020) 1200–1212 www.materialstoday.com/proceedings
2214-7853© 2019 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of SIXTH INTERNATIONAL CONFERENCE ON RECENT ADVANCES IN COMPOSITE
MATERIALS, ICRACM-2019.
ICRACM-2019
Corrosion Resistance of Electroless Ni-P-SiC/ Ni-P-TiO
2
-ZrO
2
Nano-Coatings in Paper Mill Bleach Plant
Munna Ram
a
, Manoj Kumar
a
, A. Ansari
a
, Sulaxna Sharma
b*
and Awanish Sharma
a
*
a
Department of Physics, Graphic Era Deemed To Be University, Dehradun, India
b
Department of AS&H, THDC, Institute of Hydropower Engineering and Technology, Tehri, India.
*Corresponding Authors: Email: awanishiitr@gmail.com, sulaxnasharma@gmail.com
Abstract
In present investigation, electroless Ni-P-SiC/Ni-P-TiO
2
-ZrO
2
nano-composite platings have been deposited upon mild steel
substrate (AISI 1040). A homogeneous and consistent allocation of SiC, TiO
2
and ZrO
2
nano-particles into EL Ni-P matrix is
recognized in as plated and heated (400
0
C) coupons respectively through SEM and EDAX methods. The investigated coupons
exhibited resistance against corrosion in order as: 254SMO > SS2205 > Ni-P-TiO
2
-ZrO
2
as-plated > Ni-P-TiO
2
-ZrO
2
heat treated
> Ni-P-SiC as-plated > Ni-P-SiC heat treated > SS316L. The corrosion resistance seems too dependent upon Cr, Mo and N
content and hence correlate well with the PRE number of the respective alloys. The conventional materials of construction SS
316L are not suitable for both C and D washers. Avesta 254SMO shows immunity to attack in these environments. On the basis
of corrosion resistance, mechanical properties and cost comparison, Avesta 254 SMO seems acceptable material for gaseous
phase of C and D washers while duplex stainless steel 2205 and Ni-P-SiC/Ni-P-TiO
2
-ZrO
2
as-plated and heated coatings seems
acceptable for the other application in these washers.
Keywords: Electroless coatings; corrosion; XRD; SEM- EDAX; In-plant.
1. Introduction
In the pulp and paper industry bleach plant is considered as the most corrosive section of a paper mill. This
prudence is mainly owing to (Cl
2
) chlorine and its compounds [1, 2] such as (ClO
2
) chlorine dioxide and (HClO
3
-
)