Top Curr Chem (Z) (2018) 376:8
https://doi.org/10.1007/s41061-017-0177-9
1 3
REVIEW
Chemical Valorization of Cashew Nut Shell Waste
E. B. Mubofu
1
· J. E. Mgaya
1
Received: 24 February 2017 / Accepted: 6 November 2017 / Published online: 13 February 2018
© Springer International Publishing AG, part of Springer Nature 2018
Abstract Cashew nut shells are agro-wastes produced from cashew nut processing
factories and contain about 30–35 wt% oil called cashew nut shell liquid (CNSL).
This liquid is a mixture of four potential compounds, namely anacardic acid,
cardanol, cardol and 2-methyl cardol. Various reactions have been developed to con-
vert the components of cashew nut shell liquid into industrially important chemicals,
and these materials are herein described. Such reactions employed in the transfor-
mation include transfer hydrogenation reactions, isomerization reactions, metathesis
reactions, carbonylation reactions, polymerization reactions, isomerizing metathesis
reaction, and isomerizing carbonylation reactions. Through these descriptions, one
realizes that cashew nut shells are not a waste, but they are rather a good source of
a potential liquid, CNSL, which is a promising renewable resource for synthesizing
various industrial chemicals.
Keywords Cashew nut shells · Cashew nut shell liquid · Agro-wastes
1 Introduction
Cashew (Anacardium occidentale) is a tree native to Brazil, and it was introduced
to other parts of the world in the sixteenth century, mainly with the intention
of soil conservation. From its intended purpose to check soil erosion, the crop
became a major foreign exchange earner in most countries [1, 2]. It is primarily
This article is part of the Topical Collection “Chemistry and Chemical Technologies in Waste
Valorization”; edited by Carol Sze Ki LIN.
* E. B. Mubofu
ebmubofu@udsm.ac.tz; ebmubofu@gmail.com
1
Chemistry Department, University of Dar es Salaam, P.O. Box 35061, Dar es Salaam, Tanzania