Exploring impacts of vegetated buffer strips on nitrogen cycling using a spatially explicit hydro-biogeochemical modeling approach S. Klatt a , D. Kraus a , P. Kraft b , L. Breuer b , M. Wlotzka d , V. Heuveline d , E. Haas a, * , R. Kiese a , K. Butterbach-Bahl a, c a Karlsruhe Institute of Technology (KIT), Institute of Meteorology and Climate Research (IMK-IFU), Kreuzeckbahnstr.19, 82467 Garmisch-Partenkirchen, Germany b Justus-Liebig-University of Giessen, Institute of Landscape Ecology and Resources Management (ILR), Heinrich-Buff-Ring 26, 35392 Giessen, Germany c International Livestock Research Institute (ILRI), 30709 Naivasha Rd, Nairobi, Kenya d Heidelberg University, Interdisciplinary Center for Scientic Computing (IWR), Speyerer Str. 6, 69115 Heidelberg, Germany article info Article history: Received 11 February 2016 Received in revised form 29 November 2016 Accepted 3 December 2016 Keywords: Buffer strip Nitrate retention Riparian zone CMF LandscapeDNDC Model coupling abstract Agriculture has been recognized as a major anthropogenic source of surplus loads of nitrogen in the environment. Losses of nitrate via subsurface pathways are severely threatening groundwater and sur- face waters. This study explored the capability of a coupled hydro-biogeochemical spatially explicit model, simulating nitrogen cycling in agricultural soils and the associated fate of excess nitrate subjected to vertical and lateral displacement towards water bodies. Different vegetated buffer strips (VBS) were tested for their nitrate retention capability and impacts on N 2 O and N 2 emissions. The effectiveness of a VBS to remove nitrate by denitrication strongly depends on soil characteristics and hydrological ow paths. Simulated N 2 emissions from VBS with high soil moisture were up to twenty-fold compared to VBS where groundwater levels were low. Simulated streamwater nitrate concentrations without VBS were 3.7 mg NO À 3 l À1 and showed a decrease to 0.1 mg NO À 3 l À1 for a 20 m VBS. © 2016 Published by Elsevier Ltd. Software and availability Name of software CMF. Developers ILR; contact: Philipp Kraft. E-mail philipp.kraft@umwelt.uni-giessen.de. Address ILR, Heinrich-Buff-Ring 26, 35392 Giessen, Germany. Availability Open source (GNU GPLv3 license) via website http://fb09-pasig.umwelt.uni-giessen.de/cmf. Program language C/Cþþ. Program size 4 MB. Name of software LandscapeDNDC. Developers IMK-IFU, KIT; contact Ralf Kiese. E-mail ralf.kiese@kit.edu. Address IMK-IFU, KIT, Kreuzeckbahnstrasse 19, 82467 Garmisch-Partenkirchen, Germany. Availability Freeware, upon request via website http://ldndc. imk-ifu.kit.edu. Program language C/Cþþ. Program size 20 MB. 1. Introduction Nitrate (NO À 3 ) is a serious threat to surface waters and ground- water causing eutrophication. As such, it severely puts the quality of drinking water at risk (Lavelle et al., 2005; Kiese et al., 2011). According to Erisman et al. (2013) high nitrate loads were observed during 2000 and 2003 at roughly half of European groundwater and surface water monitoring stations. For example, in French Brittany approximately 80% of surface waters are estimated to exceed nitrate levels of 50 mg l À1 set as the maximum value for drinking water by the European Commission (Molenat and Gascuel-Odoux, 2002). Efforts to establish good water quality throughout the European * Corresponding author. E-mail addresses: steffen.klatt@kit.edu (S. Klatt), david.kraus@kit.edu (D. Kraus), philipp.kraft@umwelt.uni-giessen.de (P. Kraft), lutz.breuer@umwelt.uni-giessen.de (L. Breuer), martin.wlotzka@uni-heidelberg.de (M. Wlotzka), vincent.heuveline@ uni-heidelberg.de (V. Heuveline), edwin.haas@kit.edu (E. Haas), ralf.kiese@kit.edu (R. Kiese), klaus.butterbach-bahl@kit.edu (K. Butterbach-Bahl). Contents lists available at ScienceDirect Environmental Modelling & Software journal homepage: www.elsevier.com/locate/envsoft http://dx.doi.org/10.1016/j.envsoft.2016.12.002 1364-8152/© 2016 Published by Elsevier Ltd. Environmental Modelling & Software 90 (2017) 55e67