Vol.:(0123456789) 1 3
Applied Nanoscience
https://doi.org/10.1007/s13204-019-01188-x
ORIGINAL ARTICLE
Enhanced bactericidal action and dye degradation of spicy roots’
extract‑incorporated fne‑tuned metal oxide nanoparticles
A. Haider
1
· M. Ijaz
1
· M. Imran
2
· M. Naz
3
· H. Majeed
4
· J. A. Khan
1
· M. M. Ali
5
· M. Ikram
6
Received: 24 August 2019 / Accepted: 3 October 2019
© King Abdulaziz City for Science and Technology 2019
Abstract
Nanoparticles fabricated with biological reducing agents to minimize toxic efects of chemicals are being focused worldwide.
Biologically synthesized metal oxide nanomaterials have become integral part of nanotechnology. The current work is provid-
ing an insight on ZnO nanoparticles having root extract of Z. ofcinale and A. sativum in terms of catalytic and antimicrobial
action potential. The synthesized nanoparticles were characterized by X-ray Difraction (XRD), Fourier-Transform Infra-
red Spectroscopy (FTIR), X-ray Photoelectron Spectroscopy (XPS), Ultra-Violet visible spectroscopy (UV–vis), Scanning
Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and Energy-Dispersive X-ray Spectroscopy (EDS)
analysis. The synthesized nanoparticles showed strong absorption at 365 nm with size range between 31.64 and 44 nm for
Z. ofcinale and 28–45 nm in case of A. sativum-doped ZnO as revealed by UV–vis and XRD. The Z. ofcinale-doped nano-
particles demonstrated enhanced antibacterial activity against multiple drug-resistant S. aureus at increasing concentrations
(0.5, 1.0 mg/50 µl) and also actively degraded methylene blue (MB) dye. ZnO nanoparticles synthesized by green approach
have potential to resolve emerging drug resistance against pathogenic bacterial diseases. Conclusively, signifcant inhibition
zones resulted against (MDR) S. aureus ranging 1.80–2.25 mm and 2.3–3 mm at low and high concentrations for Z. ofcinale
while, 1.7–2.05 mm and 2.2–2.7 mm for A. sativum-doped ZnO-NPs.
Keywords Metal oxide · Particle size · Diseases · Antimicrobial · Nanomaterials
Introduction
Nano-materials as “wonder of modern medicine” having
unique properties of great reaction activity and large surface
area attained much attention (El-Refai et al. 2018; Yan et al.
2012). These nano-materials with size range (1–100 nm)
have higher ability to kill etiological pathogens of various
diseases up to 650 cells relative to antibiotics which kill
half dozen (Janaki et al. 2015). Small nanoparticles (NPs)
have size dimensions around atomic level providing large
surface-to-volume ratios causing changes in physical and
chemical properties as mechanical, biological, melting point,
catalytic activity, thermal and electrical conductivities and
optical absorption compared to bulk chemical composition
(Yedurkar et al. 2016). Stable antibacterial agents are com-
posed of inorganic materials at high pressures/temperatures
to endure harsh processing conditions relative to organic
ones and are considered safe for animals and human (Sawai
2003; Jacob et al. 2014).
Commonly, inorganic materials like Ag, Au, Cu, CuO, ZnO
and TiO
2
attained signifcant antibacterial efcacy; among
* M. Ijaz
mijaz@uvas.edu.pk
* M. Ikram
dr.muhammadikram@gcu.edu.pk
1
Department of Clinical Medicine and Surgery, University
of Veterinary and Animal Sciences, Lahore 54000, Punjab,
Pakistan
2
State Key Laboratory of Chemical Resource Engineering,
Beijing Advanced Innovation Centre for Soft Matter Science
and Engineering, Beijing Engineering Center for Hierarchical
Catalysts, Beijing University of Chemical Technology,
Beijing 100029, China
3
Department of Chemistry, Government College University,
Lahore 54000, Punjab, Pakistan
4
Department of Food Sciences, Cholistan University
of Veterinary and Animal Sciences, Near DHA663100,
Bahawalpur, Pakistan
5
Institute of Biochemistry and Biotechnology, University
of Veterinary and Animal Sciences, Lahore 54000, Punjab,
Pakistan
6
Solar Cell Applications Research Lab, Department
of Physics, Government College University, Lahore 54000,
Punjab, Pakistan