Vol 12, Issue 4, 2019
Online - 2455-3891
Print - 0974-2441
BIOAVAILABILITY AND DISSOLUTION ENHANCEMENT OF GLYBURIDE NANOSUSPENSION
PRADEEP KUMAR M*, CHANDRA SEKHAR KB
Department of Pharmaceutical Sciences, Jawaharlal Nehru Technological University, Ananthapuram, Andhra Pradesh, India.
Email: pradeepbadvel98@gmail.com
Received: 22 January 2019, Revised and Accepted: 19 February 2019
ABSTRACT
Objective: The main objective was to develop nanosuspension of glyburide (GLY) by quasi emulsification solvent diffusion method and to enhance
dissolution and bioavailability characteristics of the drug GLY, an antidiabetic drug which belongs to Biopharmaceutical Classification System-II
category.
Results: From these studies, it was confirmed that drugs and excipients chosen were compatible with each other. GLY-8 was the best formulation
with a particle size of 85–96 nm with 168.7°C melting point, freely soluble in phosphate buffer pH 7.4, 93.53% drug entrapment, and 90.26±1 mV of
zeta potential. This formulation shows percentage drug release of 99.85% in 24 h. In vivo pharmacokinetic study for optimized formulation (GLY -8)
suggested that there was no reaction with the rat plasma. From the results, it was shown that C
max
and T
max
were found to be 0.604±0.03 μg/ml
and 2±1.01 h, respectively. The values of t
1/2
(h), area under the curve (AUC)
(0-t)
, and AUC
(0-∞)
were found to be 10.04 h, 2.562±0.41 μg.h/ml, and
2.147±0.45 μg.h/ml, respectively.
Conclusion: Based on the results obtained, oral administration of nanosuspension could not only provide the better absorption of poorly water
soluble drugs but may also reduce toxicity and provide a new tool in drug delivery system.
Keywords: Glyburide, Scanning electron microscopy studies, In vitro drug release, In vivo pharmacokinetic evaluation, Dissolution and bioavailability
enhancement.
INTRODUCTION
In the drug discovery and development, poor water solubility is regarded
as wide problem. More than 40% of drugs are poorly soluble in water, so
they show problems in formulating them in conventional dosage forms.
This problem is complex for Class II drugs which are poorly soluble in
aqueous and organic media. Nanosuspension preparation is preferred
for compounds that are insoluble in water (but are soluble in oil) with
high log p value. Various approaches are there to resolve problems of low
solubility and low bioavailability such as micronization, cosolvency, oily
solution, and salt formation, and some other techniques are liposomes,
emulsions, microemulsion, solid dispersion, and β-cyclodextrins inclusion
complex. In these cases, nanosuspensions are preferred. It is most suitable
for the compounds with high log p value, high melting point, and high
dose. Nanosuspensions can be used to enhance the solubility of drugs that
are poorly soluble in aqueous as well as lipid media. As a result, the rate
of flooding of the active compound increases and the maximum plasma
level is reached faster (e.g., oral or intravenous administration of the
nanosuspension). This is one of the unique advantages that it has over other
approaches for enhancing solubility. It is useful for molecules with poor
solubility, poor permeability, or both, which poses a significant challenge for
the formulators [1]. Glibenclamide which is also known as glyburide (GLY)
belongs to second-generation sulfonylurea. It is majorly used to treat non-
insulin-dependent diabetes mellitus and administered orally [2]. GLY has
been classified as the Biopharmaceutical Classification System (BCS) class-II
drug due to its low aqueous solubility, with bioavailability of 100% and huge
permeability. The solubility of GLY in gastrointestinal fluids and pH in the
gastrointestinal tract impact on its in vivo dissolution. A lot of approaches
have been made to optimize in vivo dissolution and bioavailability. However,
to predict the in vivo performance of a dosage form, it is necessary to have
an in vitro–in vivo correlation studies. The main objective of this study was
to develop nanosuspension of GLY by quasi emulsification solvent diffusion
method and also to enhance dissolution and bioavailability. This manuscript
includes 12 formulations of GLY which were prepared with three different
polymers such as polyvinyl alcohol (PVA), hydroxypropyl methyl cellulose
(HPMC), and Eduragit (EDG) with a stabilizer, i.e. poloxamer 407 with
formulation codes from GLY-1 to GLY-12. The best formulation had been
identified and further subjected to both in vitro and in vivo studies [3-5].
The present study brought out the best formulation with an enhanced
dissolution and bioavailability.
MATERIALS AND METHODS
Materials
GLY drug sample was procured from Hetero Drugs, Hyderabad. HPMC
was procured from Yucca Enterprises, Mumbai. PVA was brought from
Yarrow Chem Products., Mumbai. EDG RL 100 was procured from Yucca
Enterprises, Mumbai. Poloxamer 407 was procured from SD Fine Chem,
Hyderabad. All other chemicals and reagents utilized in the study were
with the analytical grade.
Analytical method development
Determination of λ
max
Ultraviolet (UV) spectrum of GLY was carried out in phosphate buffer
pH 7.4. 10 mg of GLY was weighed accurately and transferred to a 10 ml
© 2019 The Authors. Published by Innovare Academic Sciences Pvt Ltd. This is an open access article under the CC BY license (http://creativecommons.
org/licenses/by/4. 0/) DOI: http://dx.doi.org/10.22159/ajpcr.2019.v12i4.31657
Research Article
Methods: In this work, nanoparticles were prepared using polyvinyl alcohol, hydroxypropyl methyl cellulose, and Eudragit RL100. Twelve
formulations of GLY (GLY-1–GLY-12) were formulated using the excipients at various compositions. Drug and excipient compatibility studies were
conducted using Fourier transform infrared and differential scanning calorimeter. The prepared nanosuspension was analyzed using scanning
electron microscopy for surface of the particle analysis, melting point, solubility, particle charge zeta (mv), percentage drug entrapment efficiency (%),
and in vitro drug release. The optimized formulations of nanosuspension were further studied for in vivo pharmacokinetic evaluation. Reverse-phase
high-performance liquid chromatography method was developed, validated, and used for the study of these formulations in rat plasma.