351
ISSN 1062-8738, Bulletin of the Russian Academy of Sciences: Physics, 2017, Vol. 81, No. 3, pp. 351–353. © Allerton Press, Inc., 2017.
Original Russian Text © L.A. Chekanova, S.V. Komogortsev, E.A. Denisova, L.A. Kuzovnikova, I.V. Nemtsev, R.N. Yaroslavtsev, R.S. Iskhakov, 2017, published in Izvestiya Rossiiskoi
Akademii Nauk, Seriya Fizicheskaya, 2017, Vol. 81, No. 3, pp. 380–382.
Ferromagnetic Resonance Linewidth in Powders Consisting
of Core–Shell Particles
L. A. Chekanova
a
, S. V. Komogortsev
a,
*, E. A. Denisova
a, b
, L. A. Kuzovnikova
c
,
I. V. Nemtsev
a
, R. N. Yaroslavtsev
a, b
, and R. S. Iskhakov
a
a
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036 Russia
b
Siberian Federal University, Krasnoyarsk, 660041 Russia
c
Krasnoyarsk Institute of Railway Engineering, Irkutsk State Railway Transport Engineering University,
Krasnoyarsk, 660036 Russia
*e-mail: komogor@iph.krasn.ru
AbstractThe dependence of the ferromagnetic resonance linewidth on the thickness of nonmagnetic shells
in powders consisting of ferromagnetic core–nonferromagnetic shell composite particles is investigated. It is
found that an increase in shell thickness reduces the ferromagnetic resonance linewidth by several times,
down to values comparable to those for coatings with compositions similar to that of the particle’s core. The
observed effect is assumed to result from suppression of the inhomogeneity of demagnetizing fields in a pow-
der consisting of magnetic particles.
DOI: 10.3103/S1062873817030091
INTRODUCTION
The ferromagnetic resonance (FMR) linewidth for
the powders consisting of 3d metal particles can be as
high as several kilooersteds. For cubic phases in Fe-,
Co-, and Ni-based alloys, this is not only much larger
than the linewidth for single crystals, but also exceeds
by many times the expected linewidth for polycrystal-
line samples [1]. Dipole–dipole interaction between
neighboring particles does substantially affect both the
magnetization vector orientation and the work of
magnetization of an individual particle. In addition,
dipole–dipole interaction leads to particle agglomera-
tion with the formation of clusters with different
shapes and sizes. The effective magnetic field acting
on a powder particle is largely determined by the
demagnetizing field, which depends on the size and
shape of a particle cluster and the position the particles
inside it. The inhomogeneity of the local effective
fields eventually leads to very great FMR linewidths.
When measuring the resonance absorption of electro-
magnetic waves in a powder, this inhomogeneity is
hard to control, which sharply reduces the utility of
FMR in studying magnetic powders. The structure of
the mutual arrangement of particles in magnetic pow-
ders is poorly understood and depends on many fac-
tors, including the prehistory of different effects on a
powder. It is therefore nearly impossible to theoreti-
cally consider such inhomogeneities in FMR line-
width precisely. In this work, we isolated magnetic
particles of a powder using a nonmagnetic shell to
weaken the dipole–dipole interaction between them
to the level at which the influence of the effective field
inhomogeneity in a particle ensemble is weaker than
that of the inhomogeneity inside particles. The aim of
this work was to establish the influence a particle shell
has on FMR linewidth.
EXPERIMENTAL
We investigated two particle coating techniques:
the chemical deposition of a nonmagnetic shell on
particles of a magnetic powder poured into a solution
(series A), and chemical deposition on particles of a
magnetic powder prepared in a solution according to
the homogeneous nucleation scenario (series B). The
formation of clusters of individual particles can funda-
mentally differ for the different sample coating tech-
niques we used.
To prepare samples of series А, we used a finished
Co–P powder with a known mass, which was ground
in a mortar, mixed in a solution to form a homoge-
neous suspension, and then coated with a copper shell
from a solution containing CuSO
4
(12 g/L), trilon B
(25 g/L), formalin (25 mL/L), and NaOH (pH 12) via
chemical deposition. Knowing the weight of the pow-
der and the mass of blue copper in the solution, we cal-
culated the ratio between the two phases.
To prepare samples of series В, we first synthesized
powder (Co(Р), CoNi(P), CoFe(Р), or Fe(Р)) from a
solution containing NiSO
4
(5 g/L), CoSO
4
(25 g/L by
the example of CoNi(P) particles), Na
3
C
6
H
5
O
7
(40 g/L), and NaH
2
PO
2
(200 g/L). When the reaction