Accepted Manuscript On the mixing rules matter: The VLE predictions for binary systems Christian Luiz da Silveira, Nina Paula Gonçalves Salau PII: S0378-3812(18)30472-2 DOI: https://doi.org/10.1016/j.fluid.2018.11.013 Reference: FLUID 12000 To appear in: Fluid Phase Equilibria Received Date: 12 June 2018 Revised Date: 3 October 2018 Accepted Date: 13 November 2018 Please cite this article as: C.L. da Silveira, N.P. Gonçalves Salau, On the mixing rules matter: The VLE predictions for binary systems, Fluid Phase Equilibria (2018), doi: https://doi.org/10.1016/ j.fluid.2018.11.013. This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.