Journal of Engineering Science and Technology
Vol. 15, No. 3 (2020) 2051 - 2061
© School of Engineering, Taylor’s University
2051
THE EFFECT OF CURE ACTIVATOR
ZINC OXIDE NANOPARTICLES ON THE MECHANICAL
BEHAVIOR OF POLYISOPRENE RUBBER
NABEL KADUM ABD-ALI
Material Engineering Department, College of Engineering,
University of Al-Qadisiyah, Iraq
E-mail:nabel.abdali@qu.edu.iq
Abstract
Zinc oxide is an effective material due to its unique physical and chemical
properties. The present work use of a limited amounts of zinc oxide nanoparticles
produced by sol-gel process as an alternative to conventional zinc oxide and
investigated the effects of this material on the mechanical behaviour of rubber
recipes including cis-Polyisoprene rubber vulcanized by sulphur. Results showed
the possibility of using nanoparticles of zinc oxide produced by chemical method
in smaller quantities to achieve better results than the conventional zinc oxide
used with rubber recipes especially (0.3 and 0.4 pphr). Results of Aging and
Swelling test confirm the validity of the use of this material and the results
showed significant improvements in these characteristics. Tensile strength about
9.8, 11.2, 13.9, 15.4 and 15.7 MPa were observed at 0.1, 0.2, 0.3, 0.4 and 0.5
pphr respectively compared to 12.6MPa was observed at 4 pphr conventional
ZnO. Also, the reduction ratio were 95%, 95%, 80%, 73%, 70% and 79% at aging
time reach to 120h for the recipes 4 pphr (conventional), 0.1, 0.2, 0.3, 0.4 and 0.5
respectively, while the swelling characteristics shows better resistance at 0.3 and
0.4 recipes pphr ZnO NPs. in toluene at room temperature. Current work supports
the trend towards reducing the amount of zinc oxide used in rubber compounds
as a cure activators agent.
Keywords: Aging, Cure activator, Polyisoprene rubber, Sol-gel process, Swelling,
Zinc oxide.