Indonesian Journal of Electrical Engineering and Computer Science
Vol.11, No.1, July 2018, pp. 209~214
ISSN: 2502-4752, DOI: 10.11591/ijeecs.v11.i1.pp209-214 209
Journal homepage: http://iaescore.com/journals/index.php/ijeecs
Effect of Deposition Temperature on Self-Catalyzed ZnO
Nanorods via Chemical Vapour Deposition Method
Shafinaz Sobihana Shariffudin, Puteri Sarah Mohamad Saad, Hashimah Hashim,
Mohamad Hafiz Mamat
NANO-Electronics Center, Faculty of Electrical Engineering, Universiti Teknologi MARA, 40450,
Shah Alam, Selangor, Malaysia
Article Info ABSTRACT
Article history:
Received Jan 29, 2018
Revised Mar 21, 2018
Accepted Apr 11, 2018
The morphological, structural, optical and electrical properties of ZnO
nanorods are investigated as a function of deposition temperature. The ZnO
nanorods were grown on ZnO seed catalyst layer at temperatures between
750
o
C – 825
o
C using thermal chemical vapour deposition method. Sample
deposited at 825
o
C showed the highest crystalline orientation. The FE-SEM
micrographs and the intense peak along (002) direction in the XRD spectra
of this sample implied that the nanorods possess c-axis orientation. PL
spectra showed two common ZnO peaks which centered at 380 nm and 540
nm. Two-point probe I-V measurement revealed ohmic behaviour with the
gold metal contact, whereby the current increase with the deposition
temperature.
Keywords:
CVD method
Self-catalyzed
Temperature
ZnO nanorods
Copyright © 2018Institute of Advanced Engineering and Science.
All rights reserved.
Corresponding Author:
Shafinaz Sobihana Shariffudin,
NANO-Electronics Center, Faculty of Electrical Engineering,
Universiti Teknologi MARA, 40450,
Shah Alam, Selangor, Malaysia.
Email: sobihana@salam.uitm.edu.my
1. INTRODUCTION
Zinc oxide (ZnO) is a II-VI semiconductor compound with a direct band gap of E
g
= 3.37 eV (at
room temperature) [1, 2] which makes it suitable for application of shortwave length optoelectronics devices,
such as light emitting diode and laser diodes. ZnO has high excitation binding energy of 60 meV, which is
three times larger than GaN (E
b
= 20 meV). This is the main advantage of ZnO as a light emitter, which
permit excitonic recombination to dominate at room temperature [3]. ZnO is commonly available in white
colour powder and has been used in so many products, such as in paints, ointments, adhesives, sealants, and
many more not forgetting in many electronics devices. ZnO thin films are highly transparent in the visible
wavelength, making it suitable for optoelectronics devices such as solar cells [4]. It has shown distinguished
properties which are semiconducting, piezoelectric, and pyroelectric properties [6]. It is chemically and
mechanically stable, non-toxic, and high abundant.
ZnO nanostructures such as nanorods and nanoflowers [5] have been grown using many deposition
methods. Among them are hydrothermal method [6], thermal chemical vapor deposition method [7],
magnetron sputtering [8], electrochemical deposition [9] and many more. Among these methods, CVD has
become one of the most favorable method to grow ZnO nanorods due to good crystalline structures of the
samples. In a conventional vapour–liquid–solid (VLS) growth mechanism to grow the ZnO nanostructures,
metals such as gold are used as the catalyst layer. Consequently, nanorods deposited by the VLS mechanism
typically contain catalyst nanoparticles at their tips [10]. However the metal catalysts will unavoidably affect
the purity of the products, and furthermore could affect the efficiency of electronics devices [11, 12].
According to Wang et.al [13], metal catalysts are not necessary needed during the growth process of the ZnO