Biogenic amines (BAs) are basic low molecular weight nitrogenous
compounds. According to their chemical structure, these compounds
can be distinguished into aliphatic (putrescine, cadaverine, spermine
and spermidine), aromatic (tyramine and 2-phenylethylamine), and
heterocyclic (histamine and tryptamine) variants (Figure 1). Another
way to classify BAs is related to the number of amino groups in their
molecular structure: monoamines, diamines and polyamines.
BAs are present in a wide variety of food products, such as fsh,
cheese, meat as well as alcoholic beverages. At low concentrations,
BAs may be of endogenous origin, while high concentrations are
typically present as a result of food decomposition.
BAs are mostly formed by microbial decarboxylation of free
amino acids during fermentation, storage or in food spoilage. For
example, BAs can be generated in cheese by the action of a broad
variety of microorganisms, including Bacillus, Clostridium, Hafnia,
Klebsiella, Morganella morganii, Proteus, Lactobacillus buchneri
and Lactobacillus delbrueckii. Instead, Enterobacteriaceae and
Enterococcus typically grow up in fsh, meat and their products [1],
to cite but a few.
When present at low concentrations, BAs are essential for many
human and animal physiological functions but they can cause
toxicological efects to human health when large amounts are ingested.
Some of the most common aromatic amines (that is, tyramine,
tryptamine, and 2-phenylethylamine, Figure 1) display vasoconstrictor
action while others (such as histamine, Figure 1) induce a vasodilator
efect. Tyramine and 2-phenylethylamine seem to be involved in
the hypertensive crisis and are recognised to be responsible for
the dietary-induced migraine [1]. Aliphatic BAs have shown no
adverse health efect, but they can react with nitrites (usually added
as preservatives in meat) to form nitrosamines which are known to
have, inter alia, carcinogenic, teratogenic and mutagenic activity [1-
3]. Putrescine and cadaverine (Figure 1) are able to compete with
Importance of Quantitative Analysis of Toxic Biogenic Amines in Food
Matrices
Publication History:
Received: January 19, 2017
Accepted: February 22, 2018
Published: February 24, 2018
Keywords:
Biogenic amines, Food products, Microbial decarboxylation,
Chromatographic techniques
Concept Analysis Open Access
*
Corresponding Author: Prof. Roccaldo Sardella, University of Perugia,
Department of Pharmaceutical Sciences, Section of Chemistry and Technology of
Drugs, Via del Liceo 1, 06123 Perugia, Italy, Tel: +39-075-5855138, Fax: +39-075-
5855161; E-mail: roccaldo.sardella@unipg.it
Citation: Pucciarini L, Ianni F, Galarini R, Sardella R, Natalini B (2018) Importance
of Quantitative Analysis of Toxic Biogenic Amines in Food Matrices. Int J Clin Res
Trials 3: 123. doi: https://doi.org/10.15344/2456-8007/2018/123
Copyright: © 2018 Pucciarini et al. This is an open-access article distributed
under the terms of the Creative Commons Attribution License, which permits
unrestricted use, distribution, and reproduction in any medium, provided the
original author and source are credited.
histamine for the same catabolic enzymes, thus ultimately inhibiting
the efcacy of the histamine detoxifcation process and leading to the
accumulation of toxic compounds in plasma [3].
Recent studies have demonstrated a synergistic action of ethanol
and BAs. Ethanol is able to inhibit some intestinal enzymes such as
monoamine oxidases that are involved in the detoxifcation of BAs.
Moreover, alcohol and acetaldehyde can increase the permeability of
the intestinal wall leading to increased toxic efects promoted by BAs
[2]. Tis is primarily important for wine consumers that are sensitive
to these compounds [4-5].
As mentioned above, the study of BAs is gaining growing interest
mainly for their relation to food hygiene. Accordingly, the amount of
International Journal of
Clinical Research & Trials
Lucia Pucciarini
1
, Federica Ianni
1
, Roberta Galarini
2
, Roccaldo Sardella
1
* and Benedetto Natalini
1
1
University of Perugia, Department of Pharmaceutical Sciences, Section of Chemistry and Technology of Drugs, Via del Liceo 1, 06123 Perugia, Italy
2
Experimental Zooprophylactic Institute Umbria-Marche “Togo Rosati”, Via G. Salvemini, 1, 06126 Perugia, Italy
Int J Clin Res Trials IJCRT, an open access journal
ISSN: 2456-8007 Volume 3. 2018. 123
Pucciarini, et al. Int J Clin Res Trials 2018, 3: 123
https://doi.org/10.15344/2456-8007/2018/123
Figure 1: Chemical structure of biogenic amines.