Research Article
Study of Antiultraviolet Asphalt Modifiers and
Their Antiageing Effects
Jinxuan Hu,
1
Shaopeng Wu,
1
Quantao Liu,
1
María Inmaculada García Hernández,
1
Wenbo Zeng,
1
and Wenhua Xie
2
1
State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan, China
2
Wuhan Youfeng Moulding Co. Ltd., Wuhan, China
Correspondence should be addressed to Shaopeng Wu; wusp@whut.edu.cn
Received 10 June 2017; Accepted 31 July 2017; Published 7 September 2017
Academic Editor: Frederic Dumur
Copyright © 2017 Jinxuan Hu et al. Tis is an open access article distributed under the Creative Commons Attribution License,
which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Ultraviolet (UV) radiation causes serious ageing problems on pavement surface. In recent years, diferent UV blocking materials
have been used as modifers to prevent asphalt ageing during the service life of the pavement. In this study, three diferent
materials have been used as modifers in base asphalt to test their UV blocking efects: layered double hydroxides (LDHs),
organomontmorillonite (OMMT), and carbon black (CB). UV ageing was applied to simulate the ageing process and sofening
point, penetration, ductility, DSR (Dynamic Shear Rheometer) test, and Fourier Transform Infrared Spectroscopy (FTIR) test
were conducted to evaluate the anti-UV ageing efects of the three UV blocking modifers. Physical property tests show that base
asphalt was infuenced more seriously by UV radiation compared to the modifed asphalt. DSR test results indicate that the complex
modulus of asphalt before UV ageing is increased because of modifers, while the complex modulus of base asphalt afer UV ageing is
higher than that of the modifed asphalt, which shows that the UV blocking modifers promote the antiageing efects of asphalt. FTIR
test reveals that the increment of carbonyl groups and sulfoxide groups of modifed asphalt is less than that in base asphalt. Tests
indicate the best UV blocking efect results for samples with LDHs and the worst UV blocking efect results for samples with CB.
1. Introduction
Asphalt has been used for road construction for more than
a century [1–3]. Compared with cement pavement, asphalt
pavement has remarkable advantages in comfortableness
and smoothness [4, 5]. However, the UV radiation leads
to a shorter lifespan of the pavement. A set of complex
physicochemical processes happen because of the exposition
of the asphalt pavement to UV radiation and result in a harder
and more brittle asphalt [6, 7]; as a result, low temperature
cracking and fatigue cracks are more likely to occur on the
pavement [8, 9]. Under these circumstances, it is an urgent
task to develop the method to prevent the ageing of asphalt.
Termooxidative degradation of asphalt has been investi-
gated deeply, but the efects of UV radiation on asphalt binder
ageing have been given little attention in previous researches
[10]. Although some researchers [11, 12] showed that UV
radiation only afects the upper layers of asphalt pavement,
the efect of UV radiation on asphalt cannot be ignored.
Studies [13] have shown that UV radiation afer RTFOT could
age a thin flm of asphalt to the same ageing level as the one
aged by PAV in a few hours.
Researchers adopted modifers such as UV absorbents
[14, 15], LDHs [16–18], and nanomaterials [19] to improve
the UV ageing resistance of asphalt. CB is an organic
protective material with high absorbance to UV radiation, as
a UV absorber has the potential to improve the UV ageing
resistance and enhances the low temperature properties [20].
Cong et al. [10] used CB to refect and absorb UV radiation in
asphalt. Results show that low temperature properties of CB
modifed asphalt were better than unmodifed asphalt afer
UV ageing.
Montmorillonite (MMT) nanocomposite is a phyllosili-
cate nanomaterial which has been used for the modifcation
of polymers [21, 22]. Nanosize layers of MMT could be dis-
persed into the polymer matrix due to the fact that polymer
Hindawi
Advances in Materials Science and Engineering
Volume 2017, Article ID 9595239, 9 pages
https://doi.org/10.1155/2017/9595239