Materials InnovaƟons
ComputaƟonal Materials Science | Research ArƟcle | hƩp://doi.org/10.54738/MI.2022.2402
Ab-initio Investigation of Structural,
Optoelectronic, and Magnetic Properties
of SmAlO
3
OPEN ACCESS
Received: 11 February 2022
Accepted: 13 March 2022
Published: 30 April 2022
CitaƟon: Erum N, Azhar Iqbal M, Sagar S,
Nawaz S (2022) Ab-iniƟo InvesƟgaƟon of
Structural, Optoelectronic, and MagneƟc
ProperƟes of SmAlO
3
. Materials
InnovaƟons 2 (4), 123-131.
*
Correspondence: (Nazia Erum)
nazia.erum@phys.uol.edu.pk
Copyright: © 2022 Erum N, Azhar
Iqbal M, Sagar S, Nawaz S. This is an open
access arƟcle distributed under the terms
of the CreaƟve Commons AƩribuƟon
License, which permits unrestricted use,
distribuƟon, and reproducƟon in any
medium, provided the original author and
source are credited.
Published By Hexa Publishers
ISSN
Electronic: 2790-1963
Nazia Erum
1,2*
, Muhammad Azhar Iqbal
2
, Sadia Sagar
1
, Sher Nawaz
1
1 Physics Department, The University of Lahore, New Campus, Defense Road, 54000, Lahore, Pakistan
2 Department of Physics, University of the Punjab, QuaidAzam Campus, 54000, Lahore, Pakistan
The cubic perovskites have aƩained great importance in magneto-electronic
storage devices due to their electromagneƟc nature and because of their direct
band-gap. The cubic perovskites’ structural, electronic, opƟcal, and magneƟc
characterisƟcs were invesƟgated using Density FuncƟonal Theory (DFT), using
Wein2k-code with the Full PotenƟal Linearized Augmented Plane Wave (FP-
LAPW) method. In Kohn-sham equaƟons, the Generalized Gradient ApproximaƟon
(GGA) has been used as an exchange-correlaƟon funcƟon. InvesƟgated structural
properƟes by analyƟcal methods as well as DFT establish to be similar in
comparison with the results of experimental data. The opƟmizaƟons of the stable
magneƟc phase authenƟcate the low-temperature experimental observaƟons.
The opƟcal spectra also deliver various linear opƟcal parameters. So the current
invesƟgaƟon signifies a valuable approach to analyze the comprehensive data
about structural, magneto-electronic, and opƟcal properƟes that can create a
prospect to comprehend profuse physical occurrences of SmAlO
3
. In addiƟon to it,
authorize material scienƟsts to implement the material for valuable applicaƟons.
Keywords: Opto-Electronic properties, Magnetic properties, ab-initio method
INTRODUCTION
I
n a variety of optoelectronic and pho-
tonic device applications, perovskite
materials have been reported as the
most attractive and efficient reduced
energy materials. Perovski’s invention of
calcium titanate (CaTiO3) in 1839 was
regarded as the beginning of perovskite,
and minerals with about the same crys-
tal structure as CaTiO3 were referred to
as perovskite materials (structure). Per-
ovskite materials have the chemical for-
mula ABX3, in which A and B are
cations, with A usually bigger than B,
and X is the anion, which is usually
oxides or halogens. Perovskite materi-
als have piqued interest in optoelectronic
and photovoltaic technology due to their
unusual physical properties, their absorp-
tion coefficient is high, and they have
long-range bipolar charge transfer, and
low exciting-binding energy, high dielec-
tric constant, and ferroelectric charac-
teristics, among other things. Miyasaka
et al.
1
accomplished the first success
in methyl ammonium halide (MAX
3
)
perovskites by using MAX
3
perovskites
as light-absorbing materials in a photo-
voltaic device. They are attractive materi-
als for solar applications because of their
high absorption coefficient, long dif-
fusion length, superior charge-transport
characteristics, low nonradioactive rad-
Materials InnovaƟons | 2022 | hƩps://materialsinnovaƟons.hexapb.com/ 123