Vietnam J Math DOI 10.1007/s10013-013-0047-x Structure of Polyzetas and Lyndon Words Hoang Ngoc Minh Received: 11 October 2012 / Accepted: 17 August 2013 © Vietnam Academy of Science and Technology (VAST) and Springer Science+Business Media Singapore 2013 Abstract The effective construction of pairs of bases in duality for quasi-shuffle bialgebras and the infinite factorizations by Lyndon words of noncommutative generating series allow to prove that the algebra of polyzetas is graded by the weight and therefore lead to some consequences for their arithmetical nature. Keywords Algebraic computation · Combinatorial Hopf algebra · Drinfel’d associators · Free Lie algebra · Noncommutative symbolic computation · Polylogarithm · Polyzeta · Renormalization · Regularization · Special functions · Transcendence basis Mathematics Subject Classification (2000) 05E · 11M32 · 37F25 · 68W30 1 Introduction In 1734 Euler was the first to use his summation (also discovered afterwards, and inde- pendently, by Mac-Laurin) to obtain the asymptotic expansion of the following classical harmonic sums (for N,r N and N 1,r 2): N n=1 1 n = log N + γ k1 j =1 B j j 1 N j + O 1 N k , N n=1 1 n r = ζ(r) k1 j =r 1 B j r +1 j j r 1 1 N j + O 1 N k , A Pierre Cartier, pour ses 80 ans. Hoang Ngoc Minh (B ) Université Lille II, 1, Place Déliot, 59024 Lille, France e-mail: hoang.ngocminh@lipn.univ-paris13.fr Hoang Ngoc Minh LIPN—UMR 7030, CNRS, 93430 Villetaneuse, France