0016-7622/2019-93-2-171/$ 1.00 © GEOL. SOC. INDIA | DOI: 10.1007/s12594-019-1147-3
JOURNAL GEOLOGICAL SOCIETY OF INDIA
Vol.93, February 2019, pp.171-176
Uranium and Thorium Anomalies in the ~2.5 Ga Vendodu
Leucogranite, Nellore Schist Belt, SE India and its
Potential to Generate Uranium Deposits
Gaurav J. Kokandakar, Sachin S. Ghodke, Laxman B. More, B. Nagaraju,
Munjaji V. Bhosle, S.S. Sawant
#
, K. Rathna and K. Vijaya Kumar*
School of Earth Sciences, SRTM University, Nanded – 431 606, India
#Geochemistry Division, CSIR-NGRI, Uppal Road, Habsiguda, Hyderabad – 500 007, India
*E-mail: vijay_kumar92@hotmail.com
ABSTRACT
The Vendodu intrusive, emplaced at 2483±3 Ma within the
Nellore schist belt, SE India, is a K-rich per-aluminous A-type
leucogranite composed of quartz and alkali feldspar (essential
minerals), biotite, zircon, allanite, titanite, magnetite and
apatite (magmatic accessory minerals) and muscovite, haematite,
fluorite and uraninite (hydrothermal accessory minerals); zircon
and uraninite could be both magmatic and hydrothermal. The
Vendodu leucogranite is characterized by high Rb, Zr, Nb, Th, U
and REE, low Ca, Al, Ba and Sr abundances, and large negative
Eu anomalies. U content in the Vendodu leucogranite averages
17.63 ppm and is 6 to 11 times higher than average concentration
of U in Upper Continental Crust (UCC) and Archaean granitoids.
Similarly, Th content averages 61.38 ppm and is 3 to 20 times higher
than average concentration of Th in Archaean granitoids and UCC.
The U distribution in the Vendodu leucogranite is influenced by
both magmatic and high-temperature hydrothermal processes.
Processes that have enriched U have also increased LREE, Nb and
Cr contents in the leucogranites. Geochemical proxies including
Th/U, Zr/U and V/Yb suggest both magmatic and high-T
hydrothermal (deuteric) enrichment of U over a wide range of
temperatures and oxygen fugacities. High Th/U ratios in the
Vendodu leucogranite (1.62–9.76) hint that the hydrothermal
(deuteric) fluids were possibly magmatic. Petrographic and
geochemical evidences suggest that the Vendodu leucogranite
experienced magmatic and deuteric U enrichment that has
potential to form mineralized zones either in situ or in pegmatitic
veins.
INTRODUCTION
Archaean granitoids record evolution of the early continental crust
and its ore deposits. Sites, rates and processes of crust formation
significantly changed at the Archaean-Proterozoic boundary: the Na-
rich granites of the early Archaean are largely succeeded by late
Archaean K-rich granites (Kemp and Hawkesworth, 2003), which
make up 20% of presently exposed Archaean cratons (Condie, 1993).
The K-rich leucogranites contain high proportions of radioactive
elements and are considered to have increased the upper crustal budget
of K, Rb, Cs, U, Th, LREE, Zr, and Hf, and possibly form the sources
for Palaeoproterozoic uraniferous conglomerates as well as
unconformity-related U deposits in the Palaeoproterozoic intra-cratonic
basins (Taylor, 1987; Cuney, 2014).
Uranium ores are characterized by a spectrum of compositions
resulting from different geologic origins (Cuney, 2009). Spatio-
temporally, the U-deposits range from Archaean-Proterozoic boundary
to Recent and deep-seated magmatic cumulates to surface regoliths
(Sarangi and Krishnamurthy, 2008; Cuney, 2009). The International
Atomic Energy Agency (IAEA) proposed 15 distinct types of U
deposits (Hore-Lacy, 2016). Granite-hosted uranium mineralization
is one of the important U-deposits (magmatic and hydrothermal vein-
type) (Cuney, 2009). Leucogranite hosted U deposits, in general, are
low grade (<0.1 wt.% U) but large tonnage (>100 Mt) (Cuney, 2014).
Four types of U deposits associated with leucogranites include: (1)
primary disseminations and segregations, (2) primary mineralization
in aplites and pegmatites (late differentiates; syngenetic), (3) high-T
hydrothermal deposition in veins and fractures (epigenetic) and
(4) low-T hydrothermal deposits due to meteoric water interaction
(Cuney, 2009 and 2014).
In the present study, positive uranium anomalies in circa 2.5 Ga
Vendodu leucogranite from the Nellore schist belt, SE India and
highlight its potential to host U-deposits is reported.
GEOLOGY AND PETROGRAPHY
The curvilinear Nellore Schist Belt (NSB) is the easternmost
greenstone belt within the eastern Dharwar craton (Fig. 1A) and is
sandwiched between the granulitic rocks of the Eastern Ghats belt
(EGB) to the east and the intracratonic Cuddapah basin and TTG
gneisses to the west (Fig. 1B). The NNE-trending NSB is up to
~600 km long and 30 to 130 km wide, and is composed of amphibolites,
granite gneisses and metasediments, including banded iron formations
(Vijaya Kumar et al. 2006). The present study area in the southernmost
part of the NSB occurs between 2.7-2.6 Ga Archaean TTG to the west
and the arc-related 1.8-1.7 Ga Eastern Ghats granite-migmatite complex
to the east (Fig. 1C). Contacts between the different formations are
either thrust or high-angle reverse faults (Fig. 1C). Hornblende- and
biotite-granodiorite and leucogranite bodies are dispersed within the
amphibolites and schistose rocks around the Kandra area (Fig. 1C).
Leucogranites occur as domical stocks and elongate plutons within
the schistose rocks. The strike directions of the host NSB terrane and
the linear trails of leucogranite are conformable. A younger (1.85 Ga)
ophiolite (Leelanandam, 1990; Sesha Sai, 2009; Vijaya Kumar et al.,
2010; Saha, 2011), also occurs in the area, suggesting that the zone
experienced repeated tectonothermal events. The leucogranites show
intrusive relationships with the NSB, but thrusted and sheared contacts
with the Kandra ophiolite complex (Fig. 1C).
The Vendodu leucogranite, member of the circa 2.5 Ga K-rich
leucogranite magmatism (Vijaya Kumar et al., 2011), occurs as an
isolated stock to the southwest of Kandra ophiolite complex within
the Nellore schist belt (Fig. 1C). SHRIMP U-Pb dating of magmatic
zircons indicate that the Vendodu leucogranite was formed at 2483±3