Research Article
The Phosphatase Inhibitor Calyculin-A Impairs Clot
Retraction, Platelet Activation, and Thrombin Generation
Renáta Hudák,
1
János Vincze,
2
László Csernoch,
2
Ildikó Beke Debreceni,
1
Tamás Oláh,
2
Ferenc Erdydi,
3
Kenneth J. Clemetson,
4
and János Kappelmayer
1
1
Department of Laboratory Medicine, Faculty of Medicine, University of Debrecen, 98 Nagyerdei krt., Debrecen 4032, Hungary
2
Department of Physiology, Faculty of Medicine, University of Debrecen, 98 Nagyerdei krt., Debrecen 4032, Hungary
3
Department of Medical Chemistry, Faculty of Medicine, University of Debrecen, 98 Nagyerdei krt., Debrecen 4032, Hungary
4
Department of Hematology, Inselspital, University of Bern, Murtenstrasse 40, 3008 Bern, Switzerland
Correspondence should be addressed to J´ anos Kappelmayer; kappelmayer@med.unideb.hu
Received 2 February 2017; Revised 10 April 2017; Accepted 24 April 2017; Published 7 June 2017
Academic Editor: Marlien Pieters
Copyright © 2017 Ren´ ata Hud´ ak et al. Tis is an open access article distributed under the Creative Commons Attribution License,
which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Te aim of this study was to investigate the efect of the serine/threonine protein phosphatase inhibitor, calyculin-A (CLA), on
clot formation and on the procoagulant activity of human platelets. Platelet-rich plasma (PRP) samples were preincubated with
bufer or CLA and subsequently platelets were activated by the protease-activated receptor 1 (PAR-1) activator, thrombin receptor
activating peptide (TRAP). Clot retraction was detected by observing clot morphology up to 1 hour, phosphatidylserine- (PS-)
expression was studied by fow cytometry, and thrombin generation was measured by a fuorimetric assay. For the intracellular
Ca
2+
assay, platelets were loaded with calcium-indicator dyes and the measurements were carried out using a ratiometric method
with real-time confocal microscopy. CLA preincubation inhibited clot retraction, PS-expression, and thrombin formation. TRAP
activation elicited Ca
2+
response and PS-expression in a subset of platelets. Te activated PRP displayed signifcantly faster and
enhanced thrombin generation compared to nonactivated samples. CLA pretreatment abrogated PS-exposure and clot retraction
also in TRAP-activated samples. As a consequence of the inhibitory efect on calcium elevation and PS-expression, CLA signifcantly
downregulated thrombin generation in PRP. Our results show that CLA pretreatment may be a useful tool to investigate platelet
activation mechanisms that contribute to clot formation and thrombin generation.
1. Introduction
Platelets play a crucial role in the pathogenesis of atheroscle-
rotic diseases including acute coronary syndrome or ischemic
stroke that are leading causes of death and disability world-
wide. Tese events are triggered by disruption of the endothe-
lium and plaque rupture or during interventions on coro-
naries, when platelets are tethered to surface-bound von
Willebrand Factor (vWF), which initiates platelet activation
and allows them to adhere to subendothelial components.
Protease-activated receptor 1 (PAR-1), the primary
platelet thrombin receptor, is G-protein-coupled. Te acti-
vator of this receptor is the strongest platelet agonist and
an important contributor to atherothrombotic processes.
Modulation of the PAR-1 receptor is the target for novel
and promising antiplatelet drugs [1, 2]. PAR-1 receptor
activation via thrombin or relevant thrombin receptor
activating peptides (TRAPs) results in a series of signaling
events terminating in platelet shape change and granule
secretion via the G
12/13
proteins and intracellular calcium
release via the G
q
mediated inositol triphosphate (IP
3
)
pathway. Intracellular IP3 receptors can be directly activated
by pharmacological agents like thiomersal that has been
used previously as a calcium mobilizer and cell function-
modulating agent [3].
Serine/threonine protein phosphatases (PP) are present
in platelets predominantly as type 1 protein phosphatase
(PP1) and type 2A protein phosphatase (PP2A) subtypes.
Calyculin-A (CLA), a naturally occurring phosphatase
inhibitor, present in marine sponges, in nanomolar concen-
tration, primarily inhibits PP2A and indirectly PP1 [4, 5].
Hindawi
BioMed Research International
Volume 2017, Article ID 9795271, 10 pages
https://doi.org/10.1155/2017/9795271