RESEARCH AND DEVELOPMENT | REFRACTORY MATERIALS
34 Interceram 1-2 | 2018 www.interceram-review.info
Solution Combustion Synthesis of
Alumina Spinel and its Characterization
S.R. Ghosh
1
, S. Mukherjee
2
, S. Banerjee
1
Abstract: Refractories as liners play an important role in the metallurgical, glassmaking, steel
and ceramic industries. Spinel-based magnesium aluminate is an excellent refractory oxide for the
production of high temperature materials focusing on emerging science and technology. It offers
the attractive combination of physical and chemical properties like high mechanical strength at
elevated temperature, a high melting point, high chemical inertness and thermal stability. Normally,
this refractory material is prepared by energy-intensive high temperature solid state processing.
Is there a way to synthesize Magnesium aluminate spinel over a solution combustion low
temperature chemical route?
Keywords: alumina spinel, XRD, FTIR, morphology
1. Introduction
Refractories as liners play an important role
in the metallurgical, glassmaking and
ceramic industries [1, 2]. The main problems
faced by steel ladle refractories are corrosion
by steel slags, liquid metal abrasion, thermal
spalling, oxidation of the carbon layer, dete-
rioration of strength at high temperatures,
and molten steel penetration [3, 4]. The per-
Figure 1 DTA/TGA of alumina with a heat rate of 15 K/min (© S. Mukherjee)