Journal of Advanced Mechanical Sciences (JAMS)
ISSN: 2583-3790 (Online)
"J. Adv. Mech. Sci., vol. 1, no. 3, pp. 93-101, September 2022"
www.jamsjournal.com 93
Investigation to Evaluate the Absorption Capacity of
HApDuring Removal of Copper (II) from Aqueous
Solution
Ankit Asthana
a
*, Abhay Kumar Mishra
a
Resarch scholar, M.Tech Department of Mechanical Engineering, Goel Institute of
Technology and Management, Lucknow, Uttar Pradesh, India.
b
Assistant Professor, Department of Mechanical Engineering, Goel Institute of Technology
and Management, Lucknow, Uttar Pradesh, India
*Corresponding Author Email and Phone Number: abhay.k.mishra@goel.edu.in ,
+919792132889
Article received: 29/08/2022, Article Revised: 06/09/2022, Article Accepted: 08/09/2022
Doi: 10.5281/zenodo.7059339
© 2022 The Authors. This is an open access article distributed under the Creative Commons
Attribution License 4.0 (CC-BY), which permits unrestricted use, distribution, and
reproduction in any medium, provided the original work is properly cited.
Abstract
Present work illustrates the removal of copper ion (i.e. Cu2+) from water using
hydroxyapatite (HAp) adsorbent. HAp powder was synthesized by chemical precipitation
method. The developed HAp powders were characterized through FESEM images alongside
the EDX analysis confirming the presence of calcium and phosphorous elements. Batch
adsorption experiments were conducted mainly using HAP. The copper (II) ion adsorbed
HAp was also characterized using, FESEM and EDX analysis. On the basis of the adsorption
experimental results a treatment unit/set up has been developed for the purpose of removal of
copper from water. The adsorption candle was made by mixing HAP and activated charcoal
in a certain proportion. Activated charcoal was used mainly to increase the flow rate of water
through the adsorbent candle. Prototypes were developed to investigate the initial copper ion
concentration of 3mg/L and 6mg/L. The prototypes thus developed have proven to be
successful as more than 1000 litres of copper contaminated water has been treated whilst
maintaining the effluent copper concentration well below the permissible limit.
Keywords: Hydroxyapatite (HAp), Adsorption, Copper, Fish scale.
1. INTRODUCTION
The rapid rise in industrial development, increase in commerce, development of
hospitals and health-care facilities has led to a significant increase in waste products. A large
amount of toxic chemicals are also being generated which are highly hazardous in nature. The
heavy metals are the most hazardous waste in liquid waste. The elements that have the
specific gravity more than 5.0 alongside the atomic weights lie in the range of 63.5 and 200
are termed as heavy metals [1]. In the categories of heavy metal Cu, Pb, As, Fe, Zn, Hg, Ni,
Cr and Cd are generally found in water and are highly toxic in nature. These heavy metals are
of grave concern as these are toxic, have the affinity of bio-accumulation and are highly
recalcitrant in the nature, consequences in the severe health related problems.