Energy and exergy analysis for torrefaction of pigeon pea stalk (cajanus cajan) and eucalyptus (eucalyptus tereticornis) Rishikesh Kumar Singh a , Koushik Jena b , Jyoti Prasad Chakraborty b , Arnab Sarkar a,* a Department of Mechanical Engineering, Indian Institute of Technology (BHU), Varanasi, India b Department of Chemical Engineering & Technology, Indian Institute of Technology (BHU), Varanasi, India highlights graphical abstract Physical energy of NCG were 20 e122 kJ compared to 60e1004 kJ for chemical part. Energy of torrefied biomass decreased to 9583e10802 kJ at 300 C. Energy and exergy of both NCG and liquid increased with increase in temperature. Recuperation of energy from liquid had more potential as compared to NCG. article info Article history: Received 4 March 2020 Received in revised form 3 May 2020 Accepted 5 May 2020 Available online xxx Keywords: Pigeon pea stalk Eucalyptus Energy Exergy Irreversibility abstract Torrefaction of pigeon pea stalk and eucalyptus have been carried out in a tubular quartz reactor at a temperature range of 200e300 C with constant residence time and heating rate under nitrogen atmosphere. Under moderate torrefaction (250 C) solid yield for both types of biomass have been in the range of 63e64% with byproducts in the range of 19e29% (liquid) and 8e18% non-condensable gases (NCG). Maximum increase in HHV for pigeon pea stalk and eucalyptus have been 45.4 and 39.8%, respectively. HHV and water content of liquid product have been in the range of 7620e11200 kJ/kg and 52.8e83.5 wt%, respectively. NCG mainly consisted of CO 2 and CO with former decreasing with increase in temperature. Energy and exergy value of solid product decreased while for NCG and liquid increased with increase in temperature. Energy and exergy value of solid have been highest followed by liquid and then NCG. CO has been the main contributor in the total energy and exergy of NCG. Exergy efficiency of solid product has been in the range of 52e54% under moderate torrefaction. Irreversibility increased with increase in temperature. Recuperation of energy from byproducts (liquid and NCG) could increase the energy recovery in solid by 8e9%. © 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. * Corresponding author., E-mail address: arnab.mec@iitbhu.ac.in (A. Sarkar). Available online at www.sciencedirect.com ScienceDirect journal homepage: www.elsevier.com/locate/he international journal of hydrogen energy xxx (xxxx) xxx https://doi.org/10.1016/j.ijhydene.2020.05.045 0360-3199/© 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. Please cite this article as: Singh RK et al., Energy and exergy analysis for torrefaction of pigeon pea stalk (cajanus cajan) and eucalyptus (eucalyptus tereticornis), International Journal of Hydrogen Energy, https://doi.org/10.1016/j.ijhydene.2020.05.045