Surface-plasmon-induced photoabsorption of Ag nanoparticle
embedded a-Si solar cell
Habibuddin Shaik
a, *
, U. Basavaraju
b
, S.N. Rachith
a, c
, M. Sundaramurthy
d
,
Abdul Sattar Sheik
e
, G. Mohan Rao
f
a
Center for Nanomaterials and MEMS, Nitte Meenakshi Institute of Technology, Yelahanka, Bangalore, Karnataka, 560064, India
b
Central Manufacturing Technology Institute, Bangalore, Karnataka, 560022, India
c
Department of Mechanical Engineering, Nitte Meenakshi Institute of Technology, Yelahanka, Bangalore, Karnataka, 560064, India
d
Indian Institute of Technology, Poowai, Bombay, Maharashtra, 400076, India
e
Department of Physics, Nitte Meenakshi Institute of Technology, Yelahanka, Bangalore, Karnataka, 560064, India
f
Plasma Processing Laboratory, Department of Instrumentation and Applied Physics, Indian Institute of Science, Bangalore, Karnataka, 560012, India
article info
Article history:
Received 30 May 2017
Received in revised form
1 August 2017
Accepted 14 August 2017
Keywords:
Light trapping
Silver nanoparticles
Solar cell
Surface plasmons
Amorphous silicon
abstract
Effect of silver nanoparticles on the performance of the solar cell is presented. We fabricated an amor-
phous silicon solar cell with a high quality absorber layer, deposited by sputtering. We have investigated
the quality variation in the absorber layer with three different power modes of sputtering. The effect of
hydrogen incorporation on the bandgap, dark conductivity, photo conductivity and hence photo gain of
absorber layer is studied for the three power modes of sputtering. Silver nanoparticles are embedded in
the high quality absorber layer of the solar cell at a depth of 50 nm. We are able to visualize the effect of
surface plasmon resonance in the vicinity of 625 nm. Along with the plasmon resonance we are able to
visualize the scattering effects in the long wavelength regions. The effect of areal coverage of the silver
nanoparticles inside the absorber layer on the transmittance, J-V characteristics and external quantum
efficiency is reported. We are able to increase the light absorption in the weakly absorbing region of 600
e675 nm by incorporating silver nanoparticles. The transmission is reduced to 46.6%, and in the vicinity
of 625 nm we achieved 10.2% higher external quantum efficiency than the reference device.
© 2017 Published by Elsevier B.V.
1. Introduction
Photovoltaics, a continuously emerging technology towards
future energy production. To fully realize its potential it is always
necessary to search for the ways to reduce the manufacturing costs
of photovoltaic cells without compromising high efficiencies. Thin
film solar cells offer the advantage of controlling the cost of solar
cell as they are fabricated by thin layers of material. However, the
thinner the absorber layer more the transmission losses are, which
hampers the solar cell performance. Light trapping mechanism i.e.
confining light within the active layer to have improved light ab-
sorption, is becoming more crucial towards achieving high effi-
ciencies. In wafer based solar cells i.e bulk crystalline silicon solar
cells, enhancement in the absorption of light has been successfully
observed and achieved by surface texturing [1]. However, this
surface texturing has a little scope in thin film solar cells as the
feature size of this texturing exceeds the typical thickness of the
absorber layer of 300e2000 nm. To increase the short circuit cur-
rent, researchers have employed surface texturing and in wave-
length scale dimensions and are successful. This was possible by
directing the incoming light into the PV cell at high propagation
angles [2]. However, this hampers the cell performance as this
technique promotes surface recombination.
In the recent years, light trapping in solar cells by multiple
scattering and localized surface plasmon resonance (LSPR) by
embedded metal nanoparticles (NPs) has emerged as a novel
approach [3e7]. A suitable wavelength of visible light can excite
localized surface plasmon resonance (LSPR) in Silver (Ag) NPs. Ef-
ficiencies enhancement in photo detectors and solar cell by incor-
porating various metal NPs [8e11] is drawing tremendous interest
in the field of photovoltaics. Enhancement in light absorption
[12,13] is one of the key parameters for enhancing the efficiency of
solar cell. These NPs which exhibits LSPR can be synthesized by
various methods such as colloidal chemical methods [14],
* Corresponding author.
E-mail address: skhabibuddin@gmail.com (H. Shaik).
Contents lists available at ScienceDirect
Optical Materials
journal homepage: www.elsevier.com/locate/optmat
http://dx.doi.org/10.1016/j.optmat.2017.08.018
0925-3467/© 2017 Published by Elsevier B.V.
Optical Materials 73 (2017) 179e187