Nanoscience and Nanotechnology 2014, 4(2): 23-26
DOI: 10.5923/j.nn.20140402.01
Formation of Clusters of Impurity Atoms of Nickel in
Silicon and Controlling Their Parameters
B. A. Abdurakhmanov
1,*
, M. K. Bakhadirkhanov
1
, K. S. Ayupov
1
, H. M. Iliyev
1
,
E. B. Saitov
1
, A. Mavlyanov
1
, H. U. Kamalov
2
1
Department of Electronics and Microelectronics, Tashkent State Technical University, Tashkent, 100095, Uzbekistan
2
Department of Semiconductor Devices, Karakalpak State University, Nukus, Uzbekistan
Abstract The paper studies the possibility of self-assembly of micro-particles of impurity atoms of nickel in silicon at
certain thermodynamic conditions. It was shown that one could set the size, concentration and distribution of clusters of
impurity atoms in the silicon lattice. Also, the effect of assembly of clusters was revealed.
Keywords Single crystalline silicon, Nanoscale structures, Self-organization of clusters of impurity atoms, Ni clusters
1. Introduction
The phenomenon of self-assembly of nanoclusters of
impurity atoms interacting with lattice defects in the crystal
lattice of semiconductor is likely to be one of the promising
and novel methods for the development of nanoscale
structures.
The possibility of building clusters of impurity atoms in
semiconductors is currently being actively investigated by
many researchers [1-5]. The interest in the assembly of
nanoclusters is largely motivated by the desire to develop
nanosize structures and control their parameters, which in
turn will have given the possibility to develop novel
elements for micro- and nanoelectronics. One can evidence
that shaping of clusters of various nature significantly
depends on solubility, diffusion parameters of impurity
atoms and thermodynamic conditions as well. However,
virtually no major research has been conducted over lately
on the possibility to regulate the parameters of such
clusters.
Clusters of impurity atoms in silicon were largely
obtained by the technique of homo-epitaxial growth or
molecular-beam epitaxial growth. The authors of the
present research work propose the technology of obtaining
of self-building impurity clusters by diffusion. The above
method in contrast to the existing method of
molecular-beam epitaxy has certain advantages and does
not require complex and expensive equipment. The method
allows:
● to produce nanoscale structures throughout the entire
* Corresponding author:
bahazeb@yandex.ru (B. A. Abdurakhmanov)
Published online at http://journal.sapub.org/nn
Copyright © 2014 Scientific & Academic Publishing. All Rights Reserved
bulk of the crystal;
● to set easily the structure, composition, distribution and
ordering of nanoscale clusters;
● to obtain magnetic nanoclusters with adjustable
magnetic moment, i.e. a novel magnetic semiconductor
material;
● to control the charging state of nanoclusters in the
broad range (N+(-)n, где n>3), thus producing multiply
charged centers in the semiconductor, which might serve as
the basis for promising novel material for nanophotonics.
The possibility of building clusters of impurity atoms of
Ni in silicon and controlling their parameters is currently
investigated in the present research article. The choice of
the impurity atom is preconditioned by the fact that firstly,
its solubility and the diffusion coefficient in silicon is
comparatively higher than that of other elements of the Fe
group, and secondly, Ni will most probably turn out to be
one of the most important metals for the semiconductor
industry in the near future.
2. Main Body
2.1. Theoretical Analysis
Over the past few years, there has been a widespread
interest among experts in the field of nanotechnology and
nanoelectronics all over the world in the technology of
self-organizing impurity clusters with manageable structures
and magnetic properties. In this respect one can note some
interesting results related to implanting Co and Ge ions on Si,
ion implantation in other semiconductor materials [6-8]. As
we have heard, the technology of self-organization of
clusters of impurity atoms by using the diffusion
technologies currently is not sufficiently studied. Diffusion
technology for producing nanoscale structures is not only a