Date palm biochar-polymer composites: An investigation of electrical,
mechanical, thermal and rheological characteristics
Anesh Manjaly Poulose
a,
⁎, Ahmed Yagoub Elnour
a
, Arfat Anis
a
, Hamid Shaikh
a
, S.M. Al-Zahrani
a
,
Justin George
b
, Mohammad I. Al-Wabel
c
, Adel R. Usman
c,d
, Yong Sik Ok
e
, Daniel C.W. Tsang
f
, Ajit K. Sarmah
g
a
Chemical Engineering Department, King Saud University, Riyadh 11421, Saudi Arabia
b
Civil Engineering Department, King Saud University, Riyadh 11421, Saudi Arabia
c
Soil Sciences Department, College of Food and Agricultural Sciences, King Saud University, Riyadh 11451, Saudi Arabia
d
Soils and Water Department, Faculty of Agriculture, Assiut University, Assiut, Egypt
e
O-Jeong Eco-Resilience Institute (OJERI), Division of Environmental Science and Ecological Engineering, Korea University, Seoul, Republic of Korea
f
Department of Civil and Environmental Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China
g
Civil and Environmental Engineering Department, University of Auckland, Auckland 1142, New Zealand
HIGHLIGHTS
• Date palm waste derived biochar was
used as filler for polymer composites'
applications.
• Biochar/polypropylene (BC/PP) com-
posites' properties such as electrical,
mechanical, thermal and rheological
were investigated.
• The BC/PP composites' surface resistivi-
ty was decreased by four orders of
magnitude.
GRAPHICAL ABSTRACT
abstract article info
Article history:
Received 31 August 2017
Received in revised form 5 November 2017
Accepted 7 November 2017
Available online xxxx
The application of biochar (BC) as a filler in polymers can be viewed as a sustainable approach that incorporates
pyrolysed waste based value-added material and simultaneously mitigate bio-waste in a smart way. The over-
arching aim of this work was to investigate the electrical, mechanical, thermal and rheological properties of
biocomposite developed by utilizing date palm waste-derived BC for the reinforcing of polypropylene (PP) ma-
trix. Date palm waste derived BC prepared at (700 and 900 °C) were blended at different proportions with poly-
propylene and the resultant composites (BC/PP) were characterized using an array of techniques (scanning
electron microscope, energy-dispersive X-ray spectroscopy and Fourier transform infra-red spectroscopy). Addi-
tionally the thermal, mechanical, electrical and rheological properties of the BC/PP composites were evaluated at
different loading of BC content (from 0 to15% w/w). The mechanical properties of BC/PP composites showed an
improvement in the tensile modulus while that of electrical characterization revealed an enhanced electrical con-
ductivity with increased BC loading. Although the BC incorporation into the PP matrix has significantly reduced
the total crystallinity of the resulted composites, however; a positive effect on the crystallization temperature
(T
c
) was observed. The rheological characterization of BC/PP composites revealed that the addition of BC had
minimal effect on the storage modulus (G′) compared to the neat (PP).
© 2017 Elsevier B.V. All rights reserved.
Keywords:
Date palm waste
Biochar
Polymer composites
Electrical conductivity
Rheology
Science of the Total Environment 619–620 (2018) 311–318
⁎ Corresponding author.
E-mail address: apoulose@ksu.edu.sa (A.M. Poulose).
https://doi.org/10.1016/j.scitotenv.2017.11.076
0048-9697/© 2017 Elsevier B.V. All rights reserved.
Contents lists available at ScienceDirect
Science of the Total Environment
journal homepage: www.elsevier.com/locate/scitotenv