Materials and Corrosion. 2019;1–8. www.matcorr.com © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
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Received: 22 July 2019
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Accepted: 14 August 2019
DOI: 10.1002/maco.201911166
ARTICLE
Numerical simulation of the aluminum–zinc–steel
galvanic system for new designs of automotive chassis
Allan Ruiz‐Garcia
1
| Rodrigo Mayen‐Mondragon
1
| Joan Genesca
1
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Esteban Morales‐Murillo
2
| Jaime Taha‐Tijerina
2,3
| Rodrigo Montoya
1
1
Facultad de Química, Departamento de
Ingeniería Metalúrgica, Polo Universitario
de Tecnología Avanzada, Universidad
Nacional Autónoma de México, Apodaca,
México
2
Tecnologías de Materiales avanzados,
Metalsa S.A. de C.V., Apodaca, México
3
Engineering Department, Universidad de
Monterrey, San Pedro Garza García,
Nuevo León, México
Correspondence
Rodrigo Montoya, Facultad de Química,
Polo Universitario de Tecnología
Avanzada, Universidad Nacional
Autónoma de México, Apodaca, 66629
Nuevo León, México.
Email: rmontoyal@unam.mx
Funding information
Consejo Nacional de Ciencia y
Tecnología, Grant/Award Number:
2018‐000012‐01 NACF‐11734; Dirección
General de Asuntos del Personal
Académico, Universidad Nacional
Autónoma de México, Grant/Award
Number: TA100318
Abstract
The requirement for lighter vehicles in the automotive industry promotes
designs based on the combination of different metallic alloys. Such an approach,
however, leads to galvanic‐corrosion risks, which compromise the durability of
vehicles. One proposal to minimize such risks is to separate some of the chassis
components by a Zn washer. The present work uses the finite element method
to evaluate such an innovative design. The capacity of the washer to protect its
aluminum alloy and carbon steel neighbors is assessed. As a worst‐case
scenario, the bare metals are in contact with NaCl solution. Two electrolyte
layer thicknesses are assumed: in the micrometer and in the millimeter range.
Each case requires different mathematical models. For the thin film case, the
zinc washer is able to protect its neighbors from corrosion. However, it sustains
large corrosion rates, and thus its protection is effective only during short
periods. Furthermore, as the Zn surface degrades and thus recesses, the
“protective field” is blocked by the neighboring metal‐walls. The thicker
the electrolyte layer, the weaker the Zn protective capability and, at some point,
the corrosion of the aluminum alloy is unavoidable.
KEYWORDS
galvanic couples, modeling, thin electrolyte films
1 | INTRODUCTION
Environmental laws regulating pollutant emissions as
well as fuel consumption are becoming more strict
nowadays. In accordance with this, the automotive
industry has started a technological race to design
lighter vehicles. The main challenge is, however, the
identification of materials that could substitute
the current steels being used for vehicles chassis.
Different approaches in this direction have been taken.
For example, the development of advanced
high‐strength steels has allowed assembling thinner
structural components without affecting mechanical
performance. Another approach is the substitution of
steel by lower density materials. However, mechanical
requirements allow neither substitution of every
structural component nor the use of all material
classes. Plastics and ceramics are unfortunately not
suitable candidates in most cases. Thus, the only
practical possibilities remaining are to combine steel
parts with lighter metal parts made of, for example,
aluminum alloys (AAs). Such heterogeneous designs
lead however to one of the main technological
challenges regarding vehicles' durability: galvanic
corrosion. The phenomenon originates when metals
with different corrosion potential come in contact with