Hindawi Publishing Corporation
Journal of Nanotechnology
Volume 2011, Article ID 380979, 7 pages
doi:10.1155/2011/380979
Research Article
Antibacterial Activity of Hydrophobic Composite Materials
Containing a Visible-Light-Sensitive Photocatalyst
Kentaro Yamauchi,
1
Yanyan Yao,
2, 3
Tsuyoshi Ochiai,
2, 4
Munetoshi Sakai,
2
Yoshinobu Kubota,
3
and Goro Yamauchi
5
1
Collaborative Research Center, Daido University, 10-3 Takiharu-cho, Minami-ku, Nagoya 457-8530, Japan
2
Kanagawa Academy of Science and Technology, 3-2-1 Sakado, Takatsu-ku, Kawasaki-shi,
Kanagawa 213-0012, Japan
3
Department of Urology and Molecular Science, Graduate School of Medicine, Yokohama City University 3-9 Fukuura,
Kanazawa-ku, Yokohama 236-004, Japan
4
Division of Photocatalyst for Energy and Environment, Research Institute for Science and Technology, Tokyo University of Science,
1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
5
Department of Information Design, Daido University, 10-3 Takiharu-cho, Minami-ku, Nagoya 457-8530, Japan
Correspondence should be addressed to Goro Yamauchi, gyamauch@daido-it.ac.jp
Received 15 March 2011; Revised 25 August 2011; Accepted 7 September 2011
Academic Editor: J. Anthony Byrne
Copyright © 2011 Kentaro Yamauchi et al. This is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
The conventional superhydrophobic surface offered by PTFE provides no sterilization performance and is not sufficiently repellent
against organic liquids. These limit PTFE’s application in the field of disinfection and result a lack of durability. N-doped TiO
2
photocatalyst added PTFE composite material was developed to remedy these shortcomings. This paper reports the surface
characteristics, and the bactericidal and self-cleaning performance of the newly-developed composite material. The material
exhibited a contact angle exceeding 150 degrees consistent with its hydrophobicity despite the inclusion of the hydrophilic N-
doped TiO
2
. The surface free energy obtained for this composite was 5.8mN/m. Even when exposed to a weak fluorescent light
intensity (100 lx) for 24 hours, the viable cells of gram-negative E. coli on the 12% N-doped TiO
2
-PTFE film were reduced 5 logs.
The higher bactericidal activity was also confirmed on the gram-positive MRSA. Compared with the N-doped TiO
2
coating only,
the inactivation rate of the composite material was significantly enhanced. Utilizing the N-doped TiO
2
with the PTFE composite
coating could successfully remove, by UV illumination, oleic acid adsorbed on its surface. These results demonstrate the potential
applicability of the novel N-doped TiO
2
photocatalyst hydrophobic composite material for both indoor antibacterial action and
outdoor contamination prevention.
1. Introduction
It is well known that the conventional superhydrophobic
surface offered by polytetrafluoroethylene (PTFE) provides
no sterilization performance and is not sufficiently repellent
against organic matters. Thus, there is potential risk for
bacteria to adhere to its surface more readily in ambient
air, as well as organic matters is considered to reduce
the durability of the superhydrophobic performance. To
remedy this shortcoming, anatase titanium dioxide (TiO
2
),
a UV light-sensitive photocatalyst added water repellent
composite material has been developed in our previous
study [1–5]. TiO
2
was used to demonstrate the inactiva-
tion of various bacteria, such as Escherichia coli (E. coli),
methicillin-resistant Staphylococcus aureus (MRSA), Pseu-
domonas aeruginosa (P. aeruginosa), Legionella pneumophila
(L. pneumophila)[6–8], and Clostridium difficile spores [8].
The inclusion of TiO
2
to the PTFE coating is expected to
generate antimicrobial and self-cleaning properties, which
would expand its scope of application. Anatase TiO
2
-added
PTFE composite material is not only water-repellent but also
exhibits self-cleaning properties. However, because anatase