ORIENTAL JOURNAL OF CHEMISTRY
www.orientjchem.org
An International Open Access, Peer Reviewed Research Journal
ISSN: 0970-020 X
CODEN: OJCHEG
2019, Vol. 35, No.(1):
Pg. 404-408
This is an Open Access article licensed under a Creative Commons license: Attribution 4.0 International (CC- BY).
Published by Oriental Scientific Publishing Company © 2018
Catalytic Oxidation of C
3
-C
4
Mixture into Industrial Important
Chemical Products
TOLKYN BAIZHUMANOVA
1,2
*, SVETLANA TUNGATAROVA
1,2
, GULNAR KAUMENOVA
1,2
,
MANAPKHAN ZHUMABEK
1
and KAYSAR KASSYMKAN
1
1
D.V. Sokolsky Institute of Fuel, Catalysis and Electrochemistry, 142 Kunaev str.,
Almaty, 050010, Republic of Kazakhstan.
2
Al-Farabi Kazakh National University, Almaty, Kazakhstan.
*Corresponding author E-mail: baizhuma@mail.ru
http://dx.doi.org/10.13005/ojc/350151
(Received: September 28, 2018; Accepted: January 22, 2019)
ABSTRACT
The results of a study of the activity of polyoxide catalysts based on molybdenum, chromium
and gallium supported on natural clays for the catalytic oxidation of light alkanes to industrially
important chemical products are presented. Studies of the oxidative conversion of a propane-butane
mixture on molybdenum, chromium and gallium polyoxometallates supported on natural clays allowed
to determine that the predominant composition of the products is determined by the temperature of
the process. It was found that the production of a number of products with high yields: acetaldehyde
- at 673-723 K, acetone - at 823 K, methanol - at 673-723 K, MEK - at 773-823 K, ethanol - at
823 K, ethylene - at 673 -723 K, H2 - at 823 K is possible at oxidative conversion of propane-butane
mixture at GHSV = 450 h
-1
on the developed three-component supported Mo-Cr-Ga catalysts.
Keywords: Catalytic oxidation, Catalysts, C
3
-C
4
mixture.
INTRODUCTION
Natural and oil gases are the most
important alternative sources of raw materials,
capable in the long term to compete with oil. The
problem of rational use of C
1
-C
4
alkanes, included
in their composition, is particularly relevant in
countries rich in this type of raw materials. Despite
the huge reserves of hydrocarbon raw materials in
the Republic of Kazakhstan, it is mainly spent in
the form of domestic, industrial and motor fuel, and
the remaining raw materials are burned as part of
exhaust gases, or again pumped into oil reservoirs.
In this regard, the processing of alkanes (the main
components of natural gas and oil) for the purpose
of obtaining industrially important chemical products
is one of the most urgent environmental problems in
Kazakhstan.
Formation of synthesis gas, unsaturated
hydrocarbons, aldehydes, acids and alcohols should
be expected at incomplete oxidation of methane,