Available online at www.sciencedirect.com
ScienceDirect
Materials Today: Proceedings 24 (2020) 1376–1382 www.materialstoday.com/proceedings
2214-7853© 2018 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International Conference on Advances in Materials and
Manufacturing Applications, IConAMMA 2018.
IConAMMA 2018
Studies on Biodegradable Polyether Ester Urethanes from Natural
Resource and their Application in Coatings
Rasmika Patel
a
*, Vijayalaxmi Mishra
a
, Parth Kapatel
a
, Priyank Kachhia
a
, Mayur Pokiya
a
a
Department of Materials Science,Sardar Patel University, Vallabh vidyanagar-388120,Gujarat,India
Abstract
Polyether ester urethanes from natural resources have wide range of applications in coating and paint industries. Peanut is a
major crop of Gujarat especially of saurashtra region (India). Peanut oil contains highly unsaturated mono acids such as linoleic
acid and oleic acid which can be used for the synthesis of polyether ester urethanes. These monoacids have been allowed to react
with glycerol in presence of weak acid (Acetic acid) and strong acid (Sulfuric acid) as catalyst to prepare polyether ester polyols
(PEEP) which were further reacted with isophorone diisocyanate to synthesize polyether ester urethane (PEEU). Physico-
chemical properties of polyether ester polyol were determined by measuring acid value and intrinsic viscosity of polymers. For
determination of molecular weight and structure GPC, FTIR and NMR spectroscopy were used. Polyether ester urethanes have
been used for coating and casting purposes. Thermal stability of cured product has been determined using thermogravimetric
analysis. Mechanical properties of coating like pencil hardness, scratch hardness, adhesion and flexibility have been found out.
Being biodegradable in nature, soil degradation test of polyether ester urethanes have been performed. After continuous exposure
to moist soil, results show polyether ester urethanes started to degrade after 120 days.
© 2018 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International Conference on Advances in Materials and
Manufacturing Applications, IConAMMA 2018.
Keywords:Peanut oil; polyether ester urethane; coatings; biodegradable
1. Introduction
Vegetables oils serve as source of polymers since ancient times due to their less toxicity and easy availability in
nature [1]. Mainly vegetable oils contain high unsaturated acids which through esterification can be converted in to
* Corresponding author. Tel.: +0-989-881-0742; +0-890-507-3919
E-mail address: rasmi29@yahoo.com, parth91kapatel@gmail.com