999
ISSN 2075-1133, Inorganic Materials: Applied Research, 2019, Vol. 10, No. 4, pp. 999–1002. © Pleiades Publishing, Ltd., 2019.
Russian Text © The Author(s), 2019, published in Materialovedenie, 2019, No. 2, pp. 34–37.
The Influence of CuO Dopant Nanoparticles, Prepared
via the Arc Plasma Synthesis Method, on the Critical Current
of YBa
2
Cu
3
O
7 – δ
Composites
A. V. Ushakov
a, b,
*, I. V. Karpov
a, b
, A. A. Lepeshev
a, b
, M. I. Petrov
c
, L. Yu. Fedorov
b
,
D. M. Gokhfel’d
c
, S. M. Zharkov
b, c
, G. M. Zeer
b
, V. G. Demin
b
, and A. K. Abkaryan
b
a
Federal Research Center Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences,
Krasnoyarsk, 660036 Russia
b
Siberian Federal University, Krasnoyarsk, 660041 Russia
c
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036 Russia
*е-mail: sfu-unesco@mail.ru
Received January 11, 2018; revised April 17, 2018; accepted July 31, 2018
Abstract—YBa
2
Cu
3
O
7 – δ
–CuO composites with CuO particle contents of 0.5, 1.0, 2.0, 5.0, 10, 15, 20, and
24% were produced via arc plasma synthesis. Their magnetic properties were analyzed in the context of the
expanded critical state model. In comparison with a reference sample, the critical current intragranular den-
sity increased in composites with CuO concentrations of 0.5, 1, 20, and 24%. The mechanisms of the influ-
ence of nanodopants on the change in the critical current density at various volume contents of nano-CuO
were proposed as well.
Keywords: nanodispersed powder, high-temperature superconductor, copper oxide, vacuum arc
DOI: 10.1134/S2075113319040439
INTRODUCTION
The critical current density J
c
is an important char-
acteristic of a superconducting material in practical
applications. This quantity describes the maximum
electric current passing through a superconductor
with no energy dissipation at the given temperature
and magnetic field. In type-II superconductors (all
high-temperature superconductors (HTSC)), the
energy dissipation occurs owing to the Abrikosov vor-
tices on account of their interaction with a transport
current or the screening currents in a superconductor.
The movement of vortices may be substantially
reduced via the creation of Abrikosov vortex pinning
centers. Since the Abrikosov vortex diameter is com-
parable with the double coherence length, the prefer-
able pinning center size for HTSCs is several tens of
nanometers. The problem of the creation of pinning
centers in HTSCs, as well as their thermal and chemi-
cal stability, is thoroughly described in the literature
[1–5].
The study of transport properties of HTSC + CuO
composites simulating the network of weak S–I–S
bonds revealed that the chemical interaction of
YBa
2
Cu
3
O
7
with CuO is negligibly weak [6]. The
development of the arc plasma method for the synthe-
sis of CuO nanoscales aroused interest in the investi-
gation of the effect of CuO nanoinclusions on the
transport properties of superconducting YBa
2
Cu
3
O
7
polycrystals.
EXPERIMENTAL
Artificial pinning centers were created by using
CuO nanodispersed powders with a characteristic
granule size below 10 nm. The CuO nanopowder was
synthesized in a plasma chemical reactor in accor-
dance with a technique described in [7, 8]. The arc
evaporator used in the synthesis exhibited the follow-
ing characteristics: the pulse arc discharge current was
2.3 kA and the strength of the longitudinal magnetic
field on the cathode surface, generated by the coil, was
80 mT. The sputtering cathode was technically pure
copper. In order to activate the plasma chemical reac-
tions, the chamber was purged with a 10% О
2
+ 90%
Ar gas mixture after the pre-evacuation to a pressure of
1 mPa. The synthesis was conducted at a pressure of
10 Pa. Before the evaporation, the cathode was heated
to 700 K. The copper oxide nanopowder had a black
color. The weight concentrations of dopants were 0–
24 wt %.
YBa
2
Cu
3
O
7– δ
specimens with various CuO
nanoparticle contents were produced in accordance
with a conventional ceramic technology. A mixture of
YBa
2
Cu
3
O
7– x
powders and CuO nanoparticles was