Journal of Petroleum Technology and Alternative Fuels Vol. 3(3), pp. 29-35, March 2012
Available online at http://www.academicjournals.org/JPTAF
DOI: 10.5897/JPTAF11.031
©2012 Academic Journal
Full Length Research Paper
Quality of commercial high speed diesel and its
environmental impact
Ghulam Yasin
1
*, Muhammad Iqbal Bhanger
3
, Tariq Mahmood Ansari
1
, Syed Muhammad
Sibtain Raza Naqvi
2
and Farah Naz Talpur
3
1
Department of Chemistry Bahauddin Zakariya University, Multan 60800, Pakistan.
2
Hydrocarbon Development Institute of Pakistan, Multan, Pakistan.
3
National Centre of Excellence in Analytical Chemistry, University of Sindh, Jamshoro, Pakistan.
Accepted 10 January, 2012
Physico-chemical characteristics such as American Petroleum Institute (API) gravity, specific gravity,
pour point, kinematic viscosity, flash point, copper corrosion, conradson carbon, water and sediments,
total sulphur, residue and hydrocarbon contents (saturates, aromatics and polar) of high speed diesel
(HSD) collected from Multan regions of Pakistan have been evaluated using standard ASTM
procedures. Results have been compared with the standards specifications of European, Indian and
Pakistan to assess the quality and environmental impact.
Key words: Quality, sulphur, aromatics, environmental impact.
INTRODUCTION
Diesel is a complex mixture of hydrocarbons. Its exact
composition depends on the source of crude oil from
which it is produced and the refining methods used.
Substances derived from petroleum have great
commercial value. The customary processing of
petroleum does not involve the separation and handling
of pure hydrocarbons. Indeed, petroleum derived
products are always mixtures occasionally simple but
more often very complex. Diesel fuel oil (Conservation of
Clean Air and Water in Europe, 1998) is composed of
molecules with 15 to 25 carbons atoms and a boiling
range of 275 to 400°C. It consists of fractions, which distil
between kerosene and lubricating oil (Glumov et al.,
1997) distillates. Diesel fuel oils with higher cetane
numbers have numerous benefits including reduced
exhaust emissions and engine noise, improved cold
starting and engine durability (Guibet, 1995).
Quality of petroleum products and HSD is generally
determined by measuring various Physico-chemical
parameters such as specific gravity, kinematic viscosity,
cetane number, distillation range, residue, copper
corrosion, sediments, conradson carbon, sulphur and ash
contents, flash point, etc. following standard test methods
*Corresponding author E-mail: gyasinmalik@hotmail.com.
(Thiault, 1995; Beer, 1995; Gad, 1991; Skryabyna et al.,
1993). Due to speedy mechanization in this era, there
has been a tremendous increase in the numbers of light
and heavy vehicles in Pakistan, which resulted in a very
high demand for good quality (Brown et al., 1999) high-
speed diesel products. These petroleum products have
gained prime importance in daily life. Gas oil is used as
jet and diesel fuel and those fuels need the opposite
specification to those of an internal combustion engine.
Long chain paraffins which would cause knocking in
petrol engine are much more suitable for diesel engine.
Iso-octane is the standard for the internal combustion
engine and n-hexadecane (cetane) is the standard for the
diesel engine reference to the quality (Bureau of India
Standards, 1995) measurement. What are the
development trends, which attract our attention to diesel
engine and what are the influences, which are pertinent
to these trends.
In general they can be stated as: the cost and
availability of fuel and the demand for increased
performance. The urge for higher horsepower per cubic
inch of piston displacement, the achievement of
maximum portability per brake horsepower and the
lowering of maintenance coast and increase of engine
life, these factors are all pertinent to fuel economics in
diesel operation. The entire refinery situation in the world
has changed materially within the last several years.