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The Pharma Innovation Journal 2020; 9(5): 05-08
ISSN (E): 2277- 7695
ISSN (P): 2349-8242
NAAS Rating: 5.03
TPI 2020; 9(5): 05-08
© 2020 TPI
www.thepharmajournal.com
Received: 04-03-2020
Accepted: 06-04-2020
Yogesh P Pancham
Department of Pharmaceutical
Quality Assurance, KLE College
of Pharmacy, Belagavi, KLE
Academy of Higher Education
and Research, JNMC Campus,
Nehru Nagar, Belagavi,
Karnataka, India
Girish B
Department of Pharmaceutical
Quality Assurance, KLE College
of Pharmacy, Belagavi, KLE
Academy of Higher Education
and Research, JNMC Campus,
Nehru Nagar, Belagavi,
Karnataka, India
Shailendra Suryawanshi Sanjay
Department of Pharmaceutical
Chemistry, KLE College of
Pharmacy, Belagavi, KLE
Academy of Higher Education
and Research, JNMC Campus,
Nehru Nagar, Belagavi,
Karnataka, India
Corresponding Author:
Yogesh P Pancham
Department of Pharmaceutical
Quality Assurance, KLE College
of Pharmacy, Belagavi, KLE
Academy of Higher Education
and Research, JNMC Campus,
Nehru Nagar, Belagavi,
Karnataka, India
UV-Spectrophotometric method for quantification of
ascorbic acid in bulk powder
Yogesh P Pancham, Girish B and Shailendra Suryawanshi Sanjay
Abstract
Ascorbic acid is a potent reducing and antioxidant agent that functions in fighting bacterial infections, in
detoxifying reactions. In the present research work an attempt has been made to develop and validate
spectrophotometric method for determination of ascorbic acid in bulk powder form using UV-1900
model. The method was developed using methanol: water (50:50 v/v) as a solvent in which ascorbic acid
shows maximum absorbance wavelength at 258nm. In order to optimize the developed method,
validation of ascorbic acid were performed as per ICH guidelines parameters such as Linearity,
Selectivity, Specificity, Precision, Robustness, Ruggedness, LOD & LOQ, Solution stability were
performed. Ascorbic acid Showed linear response between concentration range of 3, 6, 9, 12, 15μg/mL
with r
2
value 0.997 all the validation report of Precision, robustness, ruggedness and solution stability
were found to be in acceptance limit. Newly developed and validated spectrophotometric method was
found to be selective, specific, linear, precise, robust, rugged and stable for determination of ascorbic
acid in bulk form using UV-1900.
Keywords: Ascorbic acid, anti-oxidant, UV-1900, ICH-guideline, stability
1. Introduction
Ascorbic acid is a six carbon compound related to glucose. It is found naturally in citrus fruits
and many vegetables. (Drug bank) L-Ascorbic acid is a white to very pale yellow crystalline
powder with a pleasant sharp acidic taste almost odourless. Ascorbic acid is a potent reducing
and antioxidant agent that functions in fighting bacterial infections, in detoxifying reactions,
and in the formation of collagen in fibrous tissue, teeth, bones, connective tissue, skin, and
capillaries
[1]
. It is available in synthetic form and well as found naturally in many medicinal
plants which includes Indian gooseberry, amla citrus fruits like limes, oranges and lemons,
green leafy vegetables
[2]
which is responsible for potent antioxidant activity.
Amla is one of the major source of Ascorbic acid. Literature survey has been done for the
content estimation of ascorbic acid in amla. Analytical methods such as UPLC (Klimczak I et
al., 2015)
[3]
HPLC (Saikh M. et al., 2013)
[4]
were reported for estimation of Ascorbic acid in
bulk. No UV-Spectrophotometric method was reported for content estimation of ascorbic acid
in amla as well as in bulk form. Hence in this research work an attempt has been made to
develop and validate UV-Spectrophotometric method by using standard ascorbic acid and
apply the same for content estimation of ascorbic acid in amla extract.
Fig 1: Chemical Structure of Ascorbic acid