71
Mater. Res. Soc. Symp. Proc. Vol. 1446 © 2012 Materials Research Society
DOI: 10.1557/opl.2012.
Role of Pt Nanoparticles in Photoreactions on TiO
2
Photoelectrodes
Woo-Jin An
1
, Wei-Ning Wang
1
, Balavinayagam Ramalingam
2
, Somik Mukherjee
2
, Dariusz M.
Niedzwiedzki
3
, Shubhra Gangopadhyay
2
, and Pratim Biswas
1
1
Aerosol and Air Quality Research Laboratory, Department of Energy, Environmental and
Chemical Engineering, Washington University in St. Louis, One Brookings Drive, Campus Box
1180, St. Louis, MO 63130, U.S.A.
2
Center for Micro/Nano Systems & Nanotechnology, University of Missouri, Columbia, MO
65211, U.S.A.
3
Photosynthetic Antenna Research Center (PARC), Washington University in St. Louis, One
Brookings Drive, St. Louis, MO 63130, U.S.A.
ABSTRACT
Highly efficient Pt-TiO
2
composite photoelectrodes were synthesized by combining two
novel deposition methods: ACVD and a room temperature RF (radio frequency) magnetron
sputtering method. A room temperature RF magnetron sputtering method allowed uniform
deposition of Pt nanoparticles (NPs) onto the as-synthesized nanostructured columnar TiO
2
films
by ACVD. Pt NP sizes from 0.5 to 3 nm demonstrating a high particle density (>10
12
cm
í2
) could
be achieved by varying deposition time with constant pressure and power intensity. As-
synthesized Pt-TiO
2
films were used as photoanodes for water photolysis. Pt nanoparticles
deposited onto the TiO
2
film for 20s produced the highest photocurrent (7.92 mA/cm
2
to 9.49
mA/cm
2
) and maximized the energy conversion efficiency (16.2 % to 21.2 %) under UV
illumination. However, as the size of Pt particles increased, more trapping sites for
photogenerated electron-hole pairs decreased photoreaction.
INTRODUCTION
Ever since Fujishima and Honda developed an innovative method to produce hydrogen
(H
2
) by water photolysis [1], much effort has been made to increase the energy conversion
efficiency. Titanium dioxide (TiO
2
) has been widely used as a photocatalytic material for solar
energy applications. Along with the wide bandgap of TiO
2
, its short electron-hole pair lifetime
[2] is a limiting factor for decomposing water into oxygen (O
2
) and hydrogen (H
2
). One
dimensional single crystal TiO
2
films provide favorable electron transport pathways, resulting in
enhanced photoreaction [3]. In addition to the film morphology, surface modification by noble
metal contacts lead to efficient electron-hole separation, improving photoelectrochemical
properties of metal oxide films [4]. Although the size of noble metal particles and the distance
between noble metal particles play a significant role in determining the efficiency of solar energy
applications [5], existing methods can not precisely control these two factors. In this study, the
room temperature RF magnetron sputtering method was employed to deposit monodispersed
nano-sized platinum (Pt) metal on the columnar TiO
2
films in a controlled manner.
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