Vol.:(0123456789) 1 3
European Journal of Wood and Wood Products
https://doi.org/10.1007/s00107-020-01503-2
ORIGINAL
Resistance against subterranean termite of beech wood impregnated
with diferent derivatives of glycerol or polyglycerol and maleic
anhydride followed by thermal modifcation: a feld test study
Mahdi Mubarok
1,2,3
· Holger Militz
2
· I. Wayan Darmawan
3
· Yusuf Sudo Hadi
3
· Stéphane Dumarçay
1
·
Philippe Gérardin
1
Received: 29 July 2019
© Springer-Verlag GmbH Germany, part of Springer Nature 2020
Abstract
Termite resistance of European beech (Fagus sylvatica) modifed with a combination of chemical and thermal methods was
investigated in feld tests. Modifcation was performed by impregnating diferent aqueous solutions of glycerol maleate or
polyglycerol maleate at diferent concentrations (10 or 40%, w/w) into the wood, followed by thermal treatment at diferent
temperatures (180, 200, or 220 °C). Field tests were conducted for one-year at Bogor, West Java, Indonesia. All wood samples
treated with the combination of chemical and thermal modifcations presented signifcantly higher termite resistance than
thermally modifed and untreated wood samples. Curing at 200 or 220 °C resulted in better performance with mass losses
due to termite attack of less than 5%.
1 Introduction
European beech (Fagus sylvatica) is one of the most impor-
tant hardwood species in Europe. It covers about 12 million
ha of territory in West and Central Europe (Cap Decision
2010), and is particularly abundant in Central Europe with an
area of more than 300,000 km
2
(Leuschner et al. 2006). This
species is used for various applications such as furniture,
fooring, decorating material, siding, chairs, table, tools,
toys or musical instruments. However, its low dimensional
stability and poor resistance to fungi and insects limit its
applications, particularly for exterior purposes like cladding
or decking. Much research has been conducted to improve
wood dimensional stability and biological durability, includ-
ing thermal and chemical modifcation. These processes
are considered as environmentally friendly alternatives to
classical treatments based on biocides (Schultz et al. 2008;
Gérardin 2016). However, most of the thermal modifcation
processes improved only dimensional stability and decay
durability, termite durability being achieved only with
chemical modifcations involving impregnation of wood
with huge amounts of chemicals. Acetylated, furfurylated
or DMDHEU (1.3-dimethylol-4.5-dihydroxyethyleneurea)
modifed wood has been reported to be resistant to termite
attack (Hadi et al. 2005; Militz et al. 2011; Bongers et al.
2015). Improving the durability of heat-treated wood to
termites might create new uses for this material, latter one
being generally not durable (Mburu et al. 2007, Shi et al.,
2007, Surini et al. 2012, Sivrikaya et al. 2015). Impregnation
with 10% aqueous polyglycerol maleate initially investigated
to fx boron (Salman et al. 2014), followed by heating at
200 or 220 °C improved termite resistance of heat-treated
wood (Salman et al. 2017). Further studies made by the same
group indicated that utilization of glycerol maleate instead
of polyglycerol maleate followed by thermal modifcation
improved resistance against the subterranean termite Reticu-
litermes flavipes in laboratory tests (Mubarok et al. 2019a,
b). The termite resistance efcacy of wood initially impreg-
nated with a 10 or 40% glycerol or polyglycerol maleate
aqueous solution followed by thermal modifcation at difer-
ent temperatures (180, 220 and 220 °C) was evaluated under
feld test conditions in a tropical area.
* Philippe Gérardin
philippe.gerardin@univ-lorraine.fr
1
Faculté des Sciences et Technologies, Université de
Lorraine, Inra, EA 4370 USC 1445 LERMAB, BP 70239,
54506 Vandoeuvre-lès-Nancy Cedex, France
2
Wood Biology and Wood Product, Faculty of Forestry,
Georg-August-Universität Göttingen, Büsgenweg 4,
37077 Göttingen, Germany
3
Wood Sciences and Technology, Faculty of Forestry, Bogor
Agricultural University (IPB), Bogor 16680, Indonesia