Research Article
Recovery of Pure Silicon and Other Materials from Disposed
Solar Cells
Lineesh Punathil ,
1
K. Mohanasundaram,
2
K. S. Tamilselavan,
3
Ravishankar Sathyamurthy ,
4
and Ali J. Chamkha
5,6
1
Department of Chemical Engineering, KPR Institute of Engineering and Technology, Coimbatore 641407, India
2
Department of Electrical and Electronics Engineering, KPR Institute of Engineering and Technology, Coimbatore 641407, India
3
Department of Electronics and Communication Engineering, KPR Institute of Engineering and Technology,
Coimbatore 641407, India
4
Department of Mechanical Engineering, KPR Institute of Engineering and Technology, Coimbatore 641407, India
5
Faculty of Engineering, Kuwait College of Science and Technology, Doha, Kuwait
6
Institute of Research and Development, Duy Tan University, Da Nang 550000, Vietnam
Correspondence should be addressed to Lineesh Punathil; lineesh.p@kpriet.ac.in and Ali J. Chamkha; alichamkha@duytan.edu.vn
Received 19 January 2021; Revised 8 March 2021; Accepted 4 April 2021; Published 16 April 2021
Academic Editor: Joaquim Carneiro
Copyright © 2021 Lineesh Punathil et al. This is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is
properly cited.
The disposal of used photovoltaic panels is increasing day by day around the world. Therefore, an efficient method for recycling
disposed photovoltaic panel is required to decrease environmental pollution. This work is aimed at efficiently recovering pure
silicon and other materials such as aluminium, silver, and lead from disposed solar cells using chemical treatments. Earlier, the
pure silicon was recovered by treating the solar cells with hydrofluoric acid or mixture of hydrofluoric acid and other chemicals.
The usage of hydrofluoric acid is eliminated in the present work as it is highly toxic and corrosive chemical. The pure silicon
(99.9984%) has been recovered by sequentially treating with three different chemicals. Aluminium, silver, and lead are also
recovered as aluminium hydroxide, silver chloride, and lead oxide, respectively.
1. Introduction
The use of solar cells has been tremendously growing around
the world as it is a nonpolluting device for power generation.
In contrary, the quantity of end-of-life of solar cells and dam-
aged solar cells is drastically increased [1]. The average life
expectancy of solar panel is about 25-30 years. In worldwide,
around 60 million tons of solar panels have become wastes as
those are in the stage of end-of-life [2]. Therefore, an efficient
method for recycling of disposed solar cells is a necessity as it
causes serious environmental pollution.
A few works have carried out for recycling of photovol-
taic panels by using various methods [3–9]. Doi et al. [3] have
recovered solar cells from EVA laminated solar cells by disso-
lution method. Later, it is found that thermal treatment is
more economical to remove EVA from solar cells [4, 5]. Fur-
ther, dissolution of EVA of solar cells in various solvents with
ultrasonic irradiation has been analyzed by Kim and Lee. [6].
Dias et al. [7] have used chemical and thermal treatments to
separate silver from the disposed solar cells.
To extract pure silicon from the solar cell, various chem-
ical treatments have been used [4, 5, 8]. Hydrofluoric acid
was the most common chemical used for separating silicon
from the solar cell [4, 5]. However, the usage of hydrofluoric
acid has to be eliminated as it is a highly toxic and corrosive
chemical. Therefore, the main objective of this work is to
replace hydrofluoric acid with other chemicals and efficiently
recover pure silicon from the disposed solar cells. In addition,
the other materials present in the solar cells such as alumin-
ium, silver, and lead have to be recovered.
Hindawi
International Journal of Photoenergy
Volume 2021, Article ID 5530213, 4 pages
https://doi.org/10.1155/2021/5530213