Current Drug T herapy
Eugenia Dumitra Teodor
1,
*
, Florentina Gatea
1
, Anton Ficai
2
and Gabriel Lucian Radu
3
1
Centre of Bioanalysis, National Institute for Biological Sciences, Bucharest, Romania;
2
Department of Science and
Engineering of Oxide Materials and Nanomaterials, Faculty of Applied Chemistry and Materials Science, University
POLITEHNICA of Bucharest, Bucharest, Romania;
3
Department of Analytical Chemistry and Instrumental Analysis,
Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest, Bucharest, Romania
A R T I C L E H I S T O R Y
Received: September 16, 2015
Revised: November 10, 2015
Accepted: November 19, 2015
DOI:
10.2174/1389450117666160208145835
Abstract: Background: In the last years, the production and applications of nanoparticles based on
iron oxides in the field of biomedicine presented a great interest due to their particular properties. Be-
cause of the expansion of the pharmaceutical industry numerous new systems for drugs delivery have
appeared, and those centered on magnetic nanoparticles are in a particular attention and in different
promising developmental stages.
Objective: In this mini review, some representative, interesting and feasible magnetic nanostructures ob-
tained recently (from last 5-6 years) with possible use in antitumor/anticancer therapy are presented.
Results: The synthesis of these nanostructures with magnetic properties implies very simple assembling
procedures and presents one of the lowest cytotoxic profiles. Magnetic nanostructures displayed possible
appliance in a large diversity of biotechnological and medical fields, both for diagnose and therapy.
Conclusion: Different types of magnetic nano-carriers loaded with different antitumor/anticancer
agents and the cases tested in vivo are considered.
Keywords: Functionalized magnetic nanostructures, anticancer therapy, drug delivery, combined drug release, imaging and
hyperthermia.
1. INTRODUCTION
In the last 10 years, many aspects about nanotechnologies
had a great impact on the researchers, mainly, but even on
administrations, industries, investors, finance organizations,
and for ordinary people. Numerous studies and experiments
were done; thus, to have a contribution in the field of new
magnetic nanostructures with biomedical applications it is
important to have a multidisciplinary approach and to have a
harmonized knowledge in many domains such us physics,
chemistry and biochemistry, biology, materials science, for
the reason that this issue is very complex. In this context, it
is important to design nanoparticle formulations with mag-
netic behavior, appropriate sizes and charging for penetrate
cells/tissues and, in the perspective of clinical applications,
with the capacity to avoid or cross the main biological barri-
ers which disturb nanoparticles to reach their target tissue or
organ [1].
For biomedical applications, nanoparticles based on iron
oxides are the main widely explored because of their specific
magnetic behavior and insignificant cytotoxicity. Magnetite
(Fe
3
O
4
) and maghemite (γ -Fe
2
O
3
), are the most frequently
used for synthesis of magnetic nanoparticles with biomedical
*Address correspondence to this author at the Centre of Bioanalysis, Faculty
Name, National Institute for Biological Sciences, Bucharest, Romania;
Tel: +40 0212200900; Fax: +40 0212200900; E-mail: eu_teodor@yahoo.com
applications ( in vitro and in vivo), and other magnetic
nanostructures based on metal alloys (e.g. FeCo, FePt,
CoPt
3
) are used, at this time, only for applications in vitro
because of their high toxicity toward living cells [2-6]. The
magnetic nanoparticles have specific physical and chemical
properties which make them applicable for different objec-
tives as well as magnetic resonance imaging and hyper-
thermia, drug delivery, cell targeting, cell labelling and bio
separation [1, 7-11]. For all mentioned purposes, high
magnetic saturation and appropriate surface functionaliza-
tion of nanoparticles are required; in addition, high bio-
compatibility is necessary [12].
In recent years, the design and application of new nano-
sized carrier systems provoked emergent attention in
nanotechnologies area [13, 14]. The nanostructures are tar-
geted to deliver different substances in a passive or in an
active way. For tumor tissues passive targeted drug delivery
can be used because of the reduced lymphatic systems of
tumor tissues and their permeable vasculature with pore di-
mensions ranging between 100 and 780 nm [15, 16]. These
features allow what is called the “enhanced permeability and
retention” effect, which permits greater accumulation of de-
livered nanoparticles at the solid tumor site. On the other
hand, for active targeted drug delivery is necessary a compli-
cated system which implies a covalent conjugation of target-
ing molecules on the nanoparticle surface, molecule which
can identify and can link to particular ligands specifically
expressed in cancer cells [17, 18].
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Current Drug Targets, 2018, 19, 239-247
239
REVIEW ARTICLE
Functionalized Magnetic Nanostructures for Anticancer Therapy