Research Article
Magnetic-Field-Enhanced Morphology of Tin Oxide
Nanomaterials for Gas Sensing Applications
Jonathan C. Briones, Gwen Castillon, Michael P. Delmo, and Gil Nonato C. Santos
Physics Department, De La Salle University, 1004 Manila, Philippines
Correspondence should be addressed to Jonathan C. Briones; jonathan.briones@dlsu.edu.ph
Received 9 March 2017; Accepted 3 May 2017; Published 18 June 2017
Academic Editor: Ciyuan Qiu
Copyright © 2017 Jonathan C. Briones et al. Tis is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
We studied the efect of an external magnetic feld (up to 0.31 T) on the growth of SnO
2
nanowires fabricated using the horizontal
vapor phase growth (HPVG) technique. Te morphology of the nanowires was characterized by using scanning electron microscopy
(SEM), and the chemical composition was characterized by energy dispersive X-ray (EDX) analysis. We found that the length of
nanowires was signifcantly enhanced by the application of EMF. Te aspect ratio, as well as the density of the fabricated nanowires,
increased with increasing magnetic feld intensity. Although the physics behind the morphology enhancement of the nanowires
under magnetic feld is still being investigated, nevertheless, we demonstrated that the magnetic feld could be used as a key
parameter to control the morphology of tin oxide nanomaterials grown via HPVG technique. Te magnetically enhanced nanowires
were used in the development of a gas sensor and were found to be sensitive to hydrogen sulfde gas and the headspace gas emitted
by spoiling meat.
1. Introduction
Tere are tremendous interests in the fabrication of vari-
ous nanomaterials with diversifed morphologies, such as
nanoparticles [1] and nanowires [2, 3], because of their
potential applications in electronics [1, 4, 5] and medicine [6].
Physical and chemical [4, 7] methods, such as thermal evap-
oration [8], chemical vapor deposition [9], sol-gel method
[10], and hydrothermal methods [8], are being used to
fabricate nanomaterials. Typically, for the physical methods,
temperature, pressure, and chemical addition [7] are the key
parameters being controlled to modify the morphologies of
nanomaterials. In this study, the parameter that was varied to
control the morphology of tin oxide (SnO
2
) nanomaterials
fabricated by using our home-developed horizontal vapor
phase growth (HVPG) technique [11] was the presence of an
external magnetic feld. Te use of a magnetic feld (0.048 T)
as an external parameter in the HVPG method was frst
reported by De Mesa et al. [6] in the synthesis of iron oxide
nanoparticles for glucose sensing applications which were
claimed to have enhanced the superparamagnetic property
of the material. No other attempts were made to fabricate
nanomaterials using the HVPG technique with external
magnetic feld as a controlling parameter.
Nanostructured SnO
2
ofers a great potential for energy
and environmental applications including gas sensing due
to large surface area, low cost, and low toxicity [4]. Its gas
sensing capabilities are widely reported due to its excep-
tionally high sensitivity to gas reaction and adsorption.
Nonetheless, much innovative science needs discovery, and
new techniques must be explored in the fabrication of this
type of material by exploiting strategies in the feld of mate-
rials science and nanotechnology. Te use of chemical and
biofunctionalized gas sensors is important in many aspects
such as personal safety and security, detection and diagnosis
of pollutants and poisons, health, semiconductor processing,
agriculture, and automotive and aerospace industries [2, 12].
Recently, it has been shown that the HVPG deposition
is successful in synthesizing nanostructured SnO
2
. However,
the said technique allows the growth of many kinds of struc-
tures along the length of the substrate. Tus, understanding
the growth mechanism of nanomaterials in HVPG technique
Hindawi
Journal of Nanomaterials
Volume 2017, Article ID 4396723, 11 pages
https://doi.org/10.1155/2017/4396723