THE OCCURRENCE AND 34 S OFAUTHIGENIC PYRITE IN MIDDLE JURASSIC BRENT GROUP SEDIMENTS D.J. Prosser*, J.A. Daws* + , A.E. Fallick** and B.P.J. Williams* Minor amounts of authigenic pyrite are common throughout the Middle Jurassic Brent Group often being well developed within the delta-plain facies of the Ness Formation. Petrographic analyses of pyrite samples from the Lyell and Murchison fields reveal two stages of pyrite authigenesis both of which occurred during an early stage of burial. The first phase of pyrite authigenesis is represented by the development of nodules and finely- disseminated cement within shale mudstone and siltstone facies and can include the development of bladed marcasite nodules. These cements are interpreted as having formed within organic-rich sediment soon after deposition and pre-date all other authigenic precipitates (typically calcite quartz and kaolinite). “Early” pyrite cements display a wide range of 34 S (-14.9 to+42.5‰CDT), and some nodules analysed display isotopically heavy cores and considerably lighter margins. These isotopically-zoned nodules are problematical. They could be interpreted as forming via progressive “closed system” bacteriogenic reduction and isotopic fractionation of sea-water sulphate, with incorporation of heavy H 2 S into the earliest-formed pyrite occurring as a result of its upward diffusion through the sediment column following isotopic fractionation at depth. However, there are a number of problems with this type of interpretation. These include the fact that diffusion will favour the 32 5 isotope so that the first-formed cements should still be isotopically “light” not “heavy”; also there is a mass-balance problem in that no low 34 S sulphides were detected. Coarsely-crystalline pyrite euhedra form nodular cements mainly within sandstones ( 34 S -2.6 to+12.8‰ CDT) and are interpreted as a “later” diagenetic phase. This second phase of sulphide cementation also pre-dates the main phases of quartz and kaolinite authigenesis within sandstones but post-dates an early phase of kaolinite and may have been partly coeval with some early calcite authigenesis. High organic contents and the early establishment of reducing conditions led to early formation of pyrite within fine-grained brackish and marine sediments. Thy lowest measured end-member 34 S of sandstone-hosted pyrite cements is less isotopically depleted than that within fine-grained argillaceous facies perhaps indicating that sandstone hosted pyrite cements began to form subsequent to the onset of burial and bacteriogenic reduction within mudstones. Compaction of marine/brackish- water shales and mudstones (or sulphate diffusion from these facies) may have supplied an already isotopically-fractionated source of sulphate to porous sandstone lithologies where “later” pyrite cements precipitated. Journal of Petroleum Geology, vol. 17(4), October 1994, pp. 407-428 407 * Dept of Geology and Petroleum Geology, Aberdeen University AB9 2UE. + Present Address: Conoco UK Exploration and Production, Park House, 116 Park Street, London W1Y 4NN. ** Scottish Universities Research and Reactor Centre, East Kilbride, Glasgow G75 0QU.