ORIGINAL ARTICLE e-ISSN: 2349-0659 p-ISSN; 2350-0964
Formulation Development, Optimization, and Characterization of
Cilnidipine-Loaded Self-microemulsifying Drug Delivery System
Kumar Anand
1
, Samit Karmakar
2
*, Pallab Mandal
1
, Md. Adil Shaharyar
1
, Rudranil Bhowmik
1
, Avishek Mondal
1
, Subhabrata Ray
3
,
Sanmoy Karmakar
1
*
A BSTRACT
Cilnidipine, a 2, 4-dihydropyridine antihypertensive, is poorly bioavailable and belongs to Biopharmaceutical Classifcation System Class II. The
present study was carried out to develop and evaluate a cilnidipine-loaded self-microemulsifying drug delivery system (SMEDDS) using food
grade oil for enhanced pharmacokinetic parameters. The SMEDDS was prepared by low-energy method. A pseudo-ternary phase diagram was
developed using triacetin, Tween 20, and Transcutol HP as oil, surfactants, and cosurfactants, respectively. The statistically optimized formulation
was obtained and was evaluated for relevant in vitro characterizations. Globule size, zeta potential, and polydispersity index (PDI) of the optimized
formulation were found to be 9.045 nm, −2.32 mv and 0.203, respectively, indicating stable and uniformly distributed microemulsion nature
of the formulation. Developed SMEDDS of viscosity 31 cps was found to be clear in 500 times dilution in water and phosphate bufer pH 1.2.
Selection of the optimized SMEDDS was followed by various formulation characteristics, including goat intestinal membrane permeability. The
in vitro dissolution study of optimized SMEDDS exhibited much better result as compared to the marketed tablet of cilnidipine.
Keywords: Biopharmaceutical classifcation system Class II, Cilnidipine, Design expert, Goat intestinal membrane permeability, Pseudo-
ternary phase diagram, Self-microemulsifying drug delivery system
Asian Pac. J. Health Sci., (2021); DOI: 10.21276/apjhs.2021.9.1.05
©2021 The Author(s). This is an open access article distributed under the terms of the Creative Commons Attribution License (http:// creativecommons.org/
licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
I NTRODUCTION
Drugs falling under Biopharmaceutical Classifcation System
(BCS) Class II and IV are known to have very low absorption,
which is difcult to overcome using conventional dosage forms.
Accordingly, lipoidal drug delivery systems might become
helpful to overcome the above-mentioned constraints and may
achieve desired clinical benefts at a lower dose with the added
advantage of reduced toxicities. Cilnidipine is one of the recently
approved drugs entity for better antihypertensive management
in comparison to other calcium channel blockers.
[1]
In the present
study, self-microemulsifying drug delivery system (SMEDDS) of
cilnidipine, a newer congener with problems characteristic of the
BCS Class II group, was developed, investigated, and evaluated.
SMEDDS, a novel drug delivery system, is an isotropic mixture of
oil, surfactant, cosurfactant, and drug. SMEDDS has the ability to
form oil-in-water (O/W) microemulsion in a spontaneous manner
under mild agitation in gastrointestinal tract fuids after oral
administration. Enhancement in the solubility and permeability
of the BCS Class II drugs, spontaneous formation, thermodynamic
stability, improved bioavailability, and feasibility of the preparation
are among the primary advantages of SMEDDS.
[2]
Here, the
presence of triglyceride in composition of self-microemulsifying
pre-concentrate is expected to enhance the bioavailability by
improving lymphatic transport bypassing the portal circulation,
which provides a greater interfacial area for absorption and
improvement of the physical and chemical stability of drugs.
[3,4]
M ATERIALS AND M ETHODS
Chemical Reagent
Triacetin (glycerol triacetate) and diethylene glycol monoethyl
ether (Transcutol HP) were purchased from Sigma-Aldrich. Tween
20, Tween 80, and Span 80 were purchased from Merck Millipore.
1
Department of Pharmaceutical Technology, Jadavpur University,
Kolkata, West Bengal, India,
2
Medical College, Kolkata, West Bengal,
India,
3
Dr. B. C. Roy College of Pharmacy and Allied Health Sciences,
Dr. Meghnad Saha Sarani, Durgapur, West Bengal, India
CorrespondingAuthor:SanmoyKarmakar,DepartmentofPharmaceutical
Technology, Director, Bio-Equivalence Study Centre, Jadavpur University,
Kolkata, West Bengal, India. E-mail: sanmoykarmakar@gmail.com
Samit Karmakar, Medical College, Kolkata, West Bengal, India.
E-mail: samitkarmakar2015@gmail.com
How to cite this article: Anand K, Mandal P, Shaharyar MA, Bhowmik R,
Mondal A, Ray S, Karmakar S. Formulation Development, Optimization,
and Characterization of Cilnidipine Loaded Self-microemulsifying
Drug Delivery System. Asian Pac. J. Health Sci., 2021;9(1):23-29.
Source of support: Nil
Conficts of interest: None.
Received: 13/08/21 Revised: 29/09/21 Accepted: 17/10/21
Labrasol was a gift sample from Gattefosse, India. Analytical grade
sodium dodecyl sulfate (SDS) was purchased from E-Merck, India.
Glycerol, isopropyl alcohol, and PEG 400 were purchased from
Merck, India. Cilnidipine was a gift from PURE CHEM PVT. LTD.,
Gujarat, India, lercanidipine, α-napthol, and ketoconazole were
obtained as a gift sample. All chemicals used were of analytical
grade. Milli-Q water was used for the present study.
Methods
Selection of oil
Selection of oil for the formulation of cilnidipine was done on the
basis of solubility of the cilnidipine in various oils. Oil, safe for chronic
use, and low cost was also a concern. Hence, solubility of cilnidipine
was determined in various oils (olive oil, almond oil, castor oil,
triacetin, sesame oil, faxseed oil, rice bran oil, and Capmul MCM).