Research Article
Transition of Dislocation Structures in Severe Plastic
DeformationandItsEffectonDissolutioninDislocationEtchant
Muhammad Rifai ,
1
Ebad Bagherpour ,
2
Genki Yamamoto,
3
Motohiro Yuasa,
1
and
Hiroyuki Miyamoto
1
1
Department of Mechanical Engineering, Doshisha University, Kyoto, Japan
2
Department of Materials Science and Engineering, School of Engineering, Shiraz University, Shiraz, Iran
3
Graduate School of Science and Engineering, Doshisha University, Kyoto, Japan
Correspondence should be addressed to Muhammad Rifai; rmuhamma@mail.doshisha.ac.jp
Received 27 September 2017; Revised 11 December 2017; Accepted 18 December 2017; Published 30 January 2018
Academic Editor: Alicia E. Ares
Copyright©2018MuhammadRifaietal.isisanopenaccessarticledistributedundertheCreativeCommonsAttribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is
properly cited.
Transition of dislocation structures in ultrafine-grained copper processed by simple shear extrusion (SSE) and its effects on
dissolutionweremanifestedbysimpleimmersiontestsusingamodifiedLivingstondislocationetchant,whichattacksdislocations
and grain boundaries selectively. e SSE process increased the internal strain evaluated by X-ray line broadening analysis until
eight passes but decreased it with further extrusion until twelve passes. e weight loss in the immersion tests reflected the
variationintheinternalstrain:namely,itincreaseduntileightpassesandthendecreasedwithfurtherextrusiontotwelvepasses.
Taking our previous report on microstructural observation into account, it is suggested that variation in the internal strain is
causedbyboththevariationindislocationdensityandstructuralchangeofgrainboundariesfromequilibriumtononequilibrium
statesorviceversa.Decreaseddislocationdensityandstructuralchangebacktoequilibriumstateofgrainboundariesinveryhigh
strainrangebypossiblydynamicrecoveryaspointedoutbyDallaTorrewerevalidatedbyX-rayanddissolutioninthemodified
Livingston etchant in addition to the direct observation by TEM reported in our former report.
1.Introduction
Grainrefinementtograinsizesbelow1 μmbysevereplastic
deformation (SPD) is now well known for improving
strengthofbulkmetallicmaterialsforstructuralapplication
[1]. Simple shear extrusion (SSE) technique is one of the
SPD methods wherein deformation proceeds by pressing
the material through a die with a specifically created direct
extrusion path [2]. SSE as well as other SPD techniques
represented by equal-channel angular pressing (ECAP) and
accumulative roll bonding (ARB) produces ultrafine grain
(UFG) materials with residual dislocation inside grains,
whichmaycauseuniquephysicalandmechanicalproperties
[3]. Dislocation density increases to the order of 10
15
m
-2
withincreasingnumberofpassesinSPD,formingfinallythe
so-called deformation-induced grain boundaries with some
dislocations remained inside grains. However, we reported
inthepreviousstudythatthesofteningoccurredwithfurther
passesafterUFGformationinpurecopperprocessedbySSE,
and this softening was considered as a result of a decrease in
dislocation density, which was revealed by scanning trans-
mission electron microscope (STEM). is decrease in dis-
location density after UFG formation may be caused by the
dynamic recovery [3–5]. As a classic approach, a dislocation
etchant has been used to locate discrete dislocations and its
densityinlowplasticstrain[6].However,itwasreportedthat
the dissolution rate in a modified solution becomes sensitive
todislocationdensityinveryhighrangeandgrainboundaries
statewithresidualdislocationsafterSPD,andthedissolution
ratewaschangedbytheflushannealinginspitethatgrainsize
is not changed [4, 7]. is study was carried out in order to
evaluate dislocation density in very high strain range using a
modified Livingston etchant which is very sensitive to dislo-
cationsandtoexaminethedissolutionbehaviorofUFGcopper.
Hindawi
Advances in Materials Science and Engineering
Volume 2018, Article ID 4254156, 6 pages
https://doi.org/10.1155/2018/4254156