Short Communication
Development of nanostructured La
0.8
Sr
0.2
MnO
3¡d
-Er
0.4
Bi
1.6
O
3
cathodes via an infiltration
process with different polymeric agents for
intermediate temperature solid oxide fuel cells
Jin Wan Park, Dong Woo Joh, Byung-Hyun Yun, Kunda J. Samdani,
Kang Taek Lee
*
Department of Energy Systems Engineering, DGIST, Daegu, 42988, South Korea
article info
Article history:
Received 30 September 2016
Received in revised form
5 November 2016
Accepted 26 November 2016
Available online xxx
Keywords:
Solid oxide fuel cells
Cathode
Bismuth oxide
Infiltration
Nanostructure
Lanthanum strontium manganite
abstract
Dual-phase composite cathodes consisting of La
0.8
Sr
0.2
MnO
3d
(LSM) nanoparticles on the
Er
0.4
Bi
1.6
O
3
(ESB) scaffold have been synthesized via an infiltration technique using
different polymeric agents for intermediate temperature solid oxide fuel cell (IT-SOFC)
applications. It was found that the LSM infiltration with Triton-X yielded well-distributed
LSM nano-catalysts (<50 nm) on the ESB surface, while the use of glycine resulted in the
highly agglomerated ‘layer-like’ structure. The nanostructured LSM-ESB fabricated with
Triton-X exhibited low electrode resistance of 0.23 U-cm
2
at 650
C, which is ~60% lower
than that of the conventional LSM-ESB (0.56 U-cm
2
). Electrochemical impedance analysis
revealed that this performance enhancement is primarily attributed to the enhanced
charge transfer process of oxygen reduction reactions with homogeneously increased re-
action sites in the characteristic nanostructure.
© 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Introduction
Lanthanum strontium manganite (LSM) is one of the widely
used cathode materials for solid oxide fuel cells (SOFCs) at
high temperatures (>800
C) due to their thermochemical
stability and high electrical conductivity. Despite its good
compatibility with conventional electrolyte materials, such as
stabilized zirconia as well as doped ceria [1], it has not been a
popular choice as a cathode material at reduced temperatures
below 750
C. This is due to its negligible ionic conductivity as
well as the high activation energy for the oxygen reduction
reaction (ORR) [2]. Recent isothermal isotope exchange studies
revealed that the oxygen incorporation into the lattice is one
* Corresponding author. DGIST, 333, Techno Jungang Daero, Hyeongpung-Myeon, Dalseong-Gun, Daegu, 42988, South Korea. Fax: þ82 53
785 6409.
E-mail address: ktlee@dgist.ac.kr (K.T. Lee).
Available online at www.sciencedirect.com
ScienceDirect
journal homepage: www.elsevier.com/locate/he
international journal of hydrogen energy xxx (2016) 1 e6
http://dx.doi.org/10.1016/j.ijhydene.2016.11.175
0360-3199/© 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Please cite this article in press as: Park JW, et al., Development of nanostructured La
0.8
Sr
0.2
MnO
3d
-Er
0.4
Bi
1.6
O
3
cathodes via an infil-
tration process with different polymeric agents for intermediate temperature solid oxide fuel cells, International Journal of Hydrogen
Energy (2016), http://dx.doi.org/10.1016/j.ijhydene.2016.11.175