1144
ISSN 0965-5441, Petroleum Chemistry, 2017, Vol. 57, No. 12, pp. 1144–1146. © Pleiades Publishing, Ltd., 2017.
Original Russian Text © O.P. Parenago, R.Z. Safieva, S.V. Antonov, N.D. Stenina, A.S. Lyadov, 2017, published in Neftekhimiya, 2017, Vol. 57, No. 6, pp. 766–768.
State-of-the-Art and Future Prospects of Production
of Biodegradable Lubricating Greases (Review)
O. P. Parenago
a,
*, R. Z. Safieva
b
, S. V. Antonov
a
, N. D. Stenina
b
, and A. S. Lyadov
a
a
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991 Russia
b
Gubkin Russian State University of Oil and Gas (National Research University), Moscow, 119991 Russia
*e-mail: parenago@ips.ac.ru
Received October 30, 2017
AbstractThe state-of-the-art and future prospects of biodegradable lubricating greases are analyzed. The
nature and properties of base oils and organic thickeners used in the production of greases are considered.
Keywords: low-temperature lubricating greases, disperse systems, organic thickener, cellulose, biodegradabil-
ity, performance characteristics
DOI: 10.1134/S0965544117060238
At the current state of development of machinery,
including transportation vehicles, the efficiency of its
functioning is mainly determined by qualified applica-
tion of lubricating materials, which include lubricating
oils, greases, surface coatings, and so on. Besides the
required technical characteristics of these materials
that provide reliable operation of all friction assem-
blies, in recent years considerable attention is drawn to
environmental aspects of production, application, and
utilization of lubricating materials [1–3].
Among lubricants, greases are of particular inter-
est. Despite the fact that their world production (about
1 million tons) is essentially inferior to that of lubricat-
ing oils (over 40 mmt), greases have undoubted advan-
tages over the oils: their lubricity is manifested over the
broader temperature range; they feature considerably
lower specific consumption and maintenance costs
and a relatively simple design of friction assemblies.
Nowadays, the development of chemistry and produc-
tion of high-performance lubricating greases is of par-
amount importance in the world; international con-
ferences and symposia are regularly held; and hun-
dreds of papers are published in leading journals.
In the context of solution of environmental issues,
the production of biodegradable greases is of increas-
ing significance, becoming the most demanding prob-
lem in the northern and arctic regions of Russia. The
development of the Russian Arctic and Far North
regions is the most important strategic problem of the
state, which is called to provide the defensive potential
of the country, the search for new deposits of mineral
resources and their extraction, as well the develop-
ment of economic and transportation infrastructure.
The application of greases in technical systems and
different friction assemblies under Arctic regions and
Far North conditions causes serious troubles associ-
ated with an increase in their dynamic viscosity, dete-
rioration of low-temperature pumpability, and proba-
ble negative consequences due to spent-grease getting
into the environment. The application of biodegrad-
able greases eliminates the necessity of both their
removing from a contaminated soil or aqueous
medium and taking measures for mitigating the conse-
quences of their disposal. The production of biode-
gradable greases and solution of environmental prob-
lems were naturally reflected in the development of
the corresponding investigations at research centers of
the Western countries. There are several high-quality
biodegradable greases on the world lubricants market;
however, the produced volumes remain low. Accord-
ing to the results of investigation of production of
lubricating oils in 2012 by the National Lubricating
Grease Institute (NLGI), only 0.42% of the total vol-
ume of manufactured products in the world is made
using base fluids which include up to 35.0% of biode-
gradable components under the conventional name
“biobase.” In Europe, their proportion is higher, mak-
ing 2.48%.
Lubricating greases, including the biodegradable
ones, are considered as disperse systems that are able
to form a three-dimensional gel-like structure under
service conditions owing to the target-oriented selec-
tion of the corresponding components of the grease.
The dispersing medium for biodegradable greases is
biobased fluids , and the dispersed phase is organic
thickeners; hence, it is recommended to use biode-
gradable additives as well.
At present, five main groups of chemical com-
pounds are considered as base oils for producing bio-
degradable greases [3]: highly unsaturated vegetable