1 Supporting Information I Primary Amino-thiourea Catalyzed Enantioselective Synthesis of Rauhut-Currier Adducts of 3-Aryl- cyclohexenone with a Tethered Enone on the Aryl Moiety at ortho-Position Sanjay Maity, Suman Sar and Prasanta Ghorai* Department of Chemistry, Indian Institute of Science Education and Research (IISER) Bhopal, Bhauri, Bhopal-462066, India. E-mail: pghorai@iiserb.ac.in Contents: Pages General Experimental Procedures 2 Materials 2 Procedure and experimental data of starting materials 3-12 Optimization Table 13-15 Reaction with phosphine catalysts 15 Experimental data of products 16-29 Reaction with cyclopentenone substrate 30 Experimental data of derivatization 30-33 References 33 Crystal Data 33